Porous organic polymers with defined morphologies: Synthesis, assembly, and emerging applications

Photoinduced morphological transformation of a self-assembled iron(ii) coordination polymer: high-performance, non-precious metal, and self-enhancing photocatalytic CO2 reduction

“…Morphology regulation is an efficient strategy to modulate the catalytic activity of heterogeneous catalysts. 25,26 As for photocatalytic CO 2 reduction, morphology-controllable photocatalysts are rarely reported. Recently, several catalysts such as porphyrin nanocrystals, 27 Cs 3 Sb 2 I 9 perovskite microcrystals, 28 and chalcogenderived conjugated organic polymers 29 have shown that photocatalytic performance on CO 2 photoreduction is highly related to their morphologies.…”

Tailoring Band Gaps in Thienyltriazine based Conjugated Porous Polymers through Comonomer Variation

“…Porous organic polymers (POPs) have gained significant recognition in comparison to their inorganic counterparts due to their remarkable chemical and physical stability, as well as their customizable structure. [1,2] This group of POPs encompasses hyper-cross-linked polymers (HCPs), [3] polymers of intrinsic microporosity (PIMs), [4] covalent triazine-based frameworks (CTFs), [5] and conjugated microporous or porous polymers (CMPs or CPPs). [6] CPPs are typically synthesized using metalcatalyzed cross-coupling reactions, direct-arylation polymerization, cyclotrimerization reaction, etc.…”

Dispersion of ultrastable crown-ether-functionalized triphenylamine and pyrene-linked porous organic conjugated polymers with single-walled carbon nanotubes as high-performance electrodes for supercapacitors

“…18 The extensive range of building blocks and reaction pathways available allows for the creation of POP materials with diverse architectures and a wide range of characteristics. 19 Materials made of POPs have a number of notable qualities, including ease of fabrication, large surface area, a variety of porosities, outstanding thermal stability, a wide light spectrum, and advantageous optoelectronic capabilities. [20][21][22] POPs are therefore suitable for a wide range of applications, including energy storage, photoredox catalysis, gas separation, ion detection, and H 2 production.…”