2021
DOI: 10.24193/subbchem.2021.01.03
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Porous silicas from mixtures of Na2Si3O7 aqueous solution and TEOS. Influence of sodium silicate amount

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“…Here, absorbance maxima corresponding to solely silicon-containing bonds are evidenced at ~1060, ~800, and ~450 cm −1 . It is interesting to note the significant decrease in the intensity of ~950 cm −1 maxima, suggesting both its dual source in the non-calcined SiO 2 /PVA_0h aging sample (vibrations of bridged Si–OH and non-bridged free Si–O– due to higher hydrolysis) and the formation of pure SiO 2 in the calcined SiO 2 _0h aging sample (the sole presence of Si–OH bonds due to increased condensation occurred after calcination) [ 71 , 72 , 73 ]. These results confirm the formation of pure, inorganic silica-based networks.…”
Section: Resultsmentioning
confidence: 99%
“…Here, absorbance maxima corresponding to solely silicon-containing bonds are evidenced at ~1060, ~800, and ~450 cm −1 . It is interesting to note the significant decrease in the intensity of ~950 cm −1 maxima, suggesting both its dual source in the non-calcined SiO 2 /PVA_0h aging sample (vibrations of bridged Si–OH and non-bridged free Si–O– due to higher hydrolysis) and the formation of pure SiO 2 in the calcined SiO 2 _0h aging sample (the sole presence of Si–OH bonds due to increased condensation occurred after calcination) [ 71 , 72 , 73 ]. These results confirm the formation of pure, inorganic silica-based networks.…”
Section: Resultsmentioning
confidence: 99%