The photocurrent generation of poly(3,4-ethylenedioxythiophene) (PEDOT) grown on TiO 2 nanoparticles were examined. PEDOT was deposited on the surface of mesoporous TiO 2 nanoparticle by chemical polymerization of 3,4-ethylenedioxythiophene (EDOT) under oxidative condition, to afford blue colored conductive particles, having average diameter of 80 nm when the feed ratio between TiO 2 and EDOT was 1:1.5 by weight. A photoelectrode coated with the PEDOT-onTiO 2 nanoparticles showed much higher photocurrent generation for a redox couple of hydroqunone and quinone, compared to that of PEDOT or TiO 2 only. The photoelectrode prepared from PEDOT-on-TiO 2 nanoparticles (ratio 1=2) showed photocurrent higher than 2.8 lA=cm 2 upon excitation with UV light under an external potential of À0.4 V (versus Ag=AgCl). The current generation and photoswitching properties was maximized when the feed ratio between TiO 2 and PEDOT was 1:2.