Porphyrin based porous organic polymers: novel synthetic strategy and exceptionally high CO<sub>2</sub>adsorption capacity

Modak, Arindam; Nandi, Mahasweta; Mondal, John; Bhaumik, Asim

doi:10.1039/c1cc14275e

Cited by 261 publications

(170 citation statements)

References 34 publications

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“…Up to now, different types of adsorbents have been used in CO 2 PSA, such as zeolites, activated carbons, silica gel, metal-organic frameworks (MOFs), and porous organic polymers [10][11][12][13][14][15]. Activated carbons generally have higher CO 2 adsorption capacity than zeolite-like materials at pressures greater than atmospheric pressure due to surface hydrophobicity, extended surface area, relatively moderate strength, easier desorption, and thermal stability [12].…”

Section: Introductionmentioning

confidence: 99%

Effect of exfoliation temperature on carbon dioxide capture of graphene nanoplates

Meng

Park

2012

Journal of Colloid and Interface Science

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Section: Introductionmentioning

confidence: 99%

Effect of exfoliation temperature on carbon dioxide capture of graphene nanoplates

Meng

Park

2012

Journal of Colloid and Interface Science

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“…[10][11][12][13][14][15] Zeolites, mesoporous silica, and MOFs show negligible CO 2 adsorption at 300°C due to their surface chemistry and structural instability. Nanoporous carbon as a non-oxide porous material has great scientific and technological applications in CO 2 adsorption.…”

Section: -4mentioning

confidence: 99%

Investigation of Narrow Pore Size Distribution on Carbon Dioxide Capture of Nanoporous Carbons

Meng¹,

Park

2012

Bulletin of the Korean Chemical Society

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Nanoporous carbons with a high specific surface area were prepared directly from thermoplastic acrylic resin as carbon precursor and MgO powder as template by carbonization over the temperature range, 500-1000 °C. The effect of the carbonization temperature on the pore structure and CO 2 adsorption capacity of the obtained porous carbon was examined. The textural properties and morphology of the porous carbon materials were analyzed by N 2 /−196 °C and CO 2 /0 °C adsorption/desorption isotherms, SEM and TEM. The CO 2 adsorption capacity of the prepared porous carbon was measured at 25 °C and 1 bar and 30 bar. The specific surface area increased from 237 to 1251 m 2 /g, and the total pore volumes increased from 0.242 to 0.763 cm 3 /g with increasing the carbonization temperature. The carbonization temperature acts mainly by generating large narrow micropores and mesopores with an average pore size dependent on the level of carbonization of the MgO-templated nanoporous carbons. The results showed that the MgO-templated nanoporous carbons at 900°C exhibited the best CO 2 adsorption value of 194 mg/g at 1 bar.

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“…Till date, however, metal complexes of those porous organic polymers are either created by the introduction of metal ions via post-functionalization [58], or by the use of predefined metal phthalocyanine [59] or porphyrin [60] building blocks as reactants. In 2012, Modak et al [61] reported a series of iron-containing porous organic polymers (Fe-POPs) through a simple one-pot bottom-up approach involving extended aromatic substitution on pyrrole with aromatic dialdehydes. The Fe-POPs possess high BET surface area (875 m 2 g −1 ) and large micropores and showed excellent CO 2 capture (~19 wt%) at 273 K/1 bar.…”

Section: Covalent Organic Frameworkmentioning

confidence: 99%

Microporous Organic Polymers for Carbon Dioxide Capture

Luo

Tan

2014

Green Chemistry and Sustainable Technology

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Microporous organic polymers (MOPs) are a unique class of porous materials consisting solely of the light elements (C, H, O, N, etc.). A series of vivid characteristics of MOPs, such as high-specific surface area, good physicochemical stability, diverse pore dimensions, topologies, and chemical functionalities, make them suitable adsorbents for CO 2 capture. In this chapter, MOPs are categorized into four classes according to the types of organic reactions and the chemical structures of the resulting materials: hypercrosslinked polymers (HCPs), covalent organic frameworks (COFs), polymers of intrinsic microporosity (PIMs), and conjugated microporous polymers (CMPs). For each type of the polymer network, the state-of-the-art development in the design, synthesis, characterization, and the CO 2 sorption performance is reviewed. Strategies for controlling CO 2 uptake capacity and adsorption enthalpy via manipulation of surface area, pore size, and functionality are discussed in detail. These studies would open up many new possibilities for the development of the novel solid sorbents targeting the CO 2 capture process. It is expected that this chapter will not only summarize the main research activities in this field, but also find possible links between basic studies and practical applications. Abbreviations ACMPAcetylene gas mediated conjugated microporous polymers BA Benzyl alcohol BC Benzyl chloride BCMA 9,10-Bis(chloromethyl)anthracene

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Porphyrin based porous organic polymers: novel synthetic strategy and exceptionally high CO₂adsorption capacity

Cited by 261 publications

References 34 publications

Effect of exfoliation temperature on carbon dioxide capture of graphene nanoplates

Effect of exfoliation temperature on carbon dioxide capture of graphene nanoplates

Investigation of Narrow Pore Size Distribution on Carbon Dioxide Capture of Nanoporous Carbons

Microporous Organic Polymers for Carbon Dioxide Capture

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Porphyrin based porous organic polymers: novel synthetic strategy and exceptionally high CO2adsorption capacity

Cited by 261 publications

References 34 publications

Effect of exfoliation temperature on carbon dioxide capture of graphene nanoplates

Effect of exfoliation temperature on carbon dioxide capture of graphene nanoplates

Investigation of Narrow Pore Size Distribution on Carbon Dioxide Capture of Nanoporous Carbons

Microporous Organic Polymers for Carbon Dioxide Capture

Contact Info

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Porphyrin based porous organic polymers: novel synthetic strategy and exceptionally high CO₂adsorption capacity