Porphyrins covalently bound to polystyrene II. an efficient model of monooxygenase reactivity

Gd26Cluster Consisting of Distorted Cubane Cores: Synthesis, Structure and Heterogeneous Catalytic Epoxidation of Olefins

“…Many attempts have been made such as intercalation or encapsulation of the metal compounds into the layered inert matrices or within the cavities of a porous solid (e.g. zeolites), [49] binding the metal compounds onto a polymeric matrix [50] and employing steric hindrance etc. [51] for easy recovery and reuse of the catalysts.…”

Biomimetic kinetics and mechanism of cyclohexene epoxidation catalyzed by metalloporphyrins

“…Thereafter various oxidants with active oxygen, e.g. hydrogen peroxide, iodosobenzene, t-butyl peroxide, m-chloroperbenzoic acid, have been employed as oxygen atom donors in combination with different metalloporphyrin catalysts [5][6][7][8][9][10][11].…”

Lanthanide Carboxylate Frameworks: Efficient Heterogeneous Catalytic System for Epoxidation of Olefins

“…Recycling of catalysts is a task of great economic and environmental advantages in chemical and pharmaceutical industry, especially when expensive and/or toxic heavy metal complexes are employed. To this end many attempts have been made, such as intercalating or encapsulating the metal complex into the layered compounds or within the cavities of a porous solid (e.g., zeolites) [34], binding the metal complex into the polymeric matrix [35], and employing the steric hindrance [36] to design recyclable catalysts. Polymer supported lanthanide-binol systems and Ln(O-iPr) 3 systems have been extensively used in catalytic oxidation of olefinic substrates [37].…”