In
this paper, the influence of Stefan flow on different reactivity coke
solution loss reaction (C
coke
+ CO
2
= 2CO) at
different temperatures were analyzed and compared to deeply understand
the mechanism of the coke solution loss reaction. Isothermal experiments
of carbon dioxide gasification with Coke A (low reactivity), Coke
B (medium reactivity), and Coke C (high reactivity), respectively,
were carried out at 1100–1300 °C. After calculation, it
is concluded that the external diffusion coefficients and the mass
transfer coefficients with Stefan flow of three kinds of coke were
decreased, and their minimum average deviations with and without Stefan
flow were 44.57/43.27/43.23 and 42.57/39.47/39.15%, respectively.
As the coke reactivity increased, the diffusion and mass transfer
capacity of carbon dioxide with Stefan flow in the boundary layer
decreased. The carbon dioxide concentration on the outer surface of
three kinds of coke with Stefan flow was less than that without Stefan
flow. The influence of Stefan flow on carbon dioxide concentration
on the outer surface of coke was increased with the increase of coke
reactivity. The area of carbon dioxide concentration region in the
three kinds of coke declined after modification, and the deviations
of the carbon dioxide concentration region area before and after modification
of three kinds of coke ranged from 6.62 to 22.85%, 7.74 to 25.17%,
and 8.62 to 26.74%. The influence of Stefan flow on the carbon dioxide
concentration region increased as coke reactivity increased.