The fast neutron
imaging technique with recoil proton detection
harbors significant potential for imaging of thick, large-scale objects
containing high-Z elements. However, the challenge to find efficient
fast neutron scintillators with high spatial resolution is ongoing.
The list of requirements for such scintillators is long and demanding:
a proton-rich, scattering-free material combining high light yield
with the absence of light reabsorption. To meet these challenges,
we look for a suitable material among a rising class of 0D organic–inorganic
Pb(II) halide hybrids. The use of large organic cations, e
.
g., trihexyltetradecylphosphonium, results in room-temperature
ionic liquids that combine highly Stokes-shifted (up to 1.7 eV), reabsorption-free,
and efficient emission (photoluminescence quantum yield up to 60%)
from molecularly small and dense (PbX
2
molar fraction up
to 0.33) emitting centers. We investigate the optical properties of
the resulting ionic liquids and showcase their utility as fast neutron
imaging scintillators. Concomitantly with good light yield, such fast-neutron
scintillators exhibit both higher spatial resolution and lower γ-ray
sensitivity compared with commercial ZnS:Cu-based screens.