Potential-assisted assembly of 1-dodecanethiol on polycrystalline gold

Influence of preparation methods on the properties of self-assembled films of octadecylphosphonate on Nitinol: XPS and EIS studies

“…The current density increase, at E ≥ 1.2 V for the NiTi/ODP imm sample, can be related to the partial stripping of the ODP layer from the NiTi surface. The potential-assisted desorption, i.e., a decrease in the surface coverage, leads to the expansion of defective sites in the ODP layer structure and finally to the surface film decomposition at nobler potentials [8]. The surface coverage, θ, of NiTi with self-assembled ODP film was calculated using the following equation:…”

“…The well accepted standard interface is the gold/thiolate [8] and copper/thiolate interfaces [9]. Interfaces of self-assembled longchain carboxylic and phosphonic acid films on metals and oxide covered metals are mechanically and chemically stable under ambient conditions [10].…”

Comparison of electrochemical oxidation of epinephrine in the presence of interfering ascorbic and uric acids on gold electrodes modified with S-functionalized compounds and gold nanoparticles

“…The SAMs of S-functionalized compounds on polycrystalline gold is a powerful method to prepare a chemical interface with stable and structurally well defined monolayers which exhibit a high degree of orientation, molecular ordering and packing density [25,26]. The material frequently used for the SAM preparation is gold because of its good affinity to sulphur and inertness [27].…”

Electroanalysis of Norepinephrine at Bare Gold Electrode Pure and Modified with Gold Nanoparticles and S‐Functionalized Self‐Assembled Layers in Aqueous Solution

“…Till the present, no publications concerning the electroanalytical determination of norepinephrine on a gold electrode modified by above mentioned reagents have been known in literature. The self-assembled layers of S-functionalized compounds on polycrystalline gold is a powerful method to prepare a chemical interface with stable and structurally well defined layers which exhibit a high degree of orientation, molecular ordering and packing density [32,33]. On the other hand, gold nanoparticle modifications could largely increase the immobilization amount of S-functionalized compounds and enhance the Au-S bond and stability of self-assembled layers, as found for those obtained with mercaptopropionic acid [34].…”