Rapid urbanization in China has strengthened the connection and cooperation among cities and has also led urban residents to be more vulnerable in adverse environmental conditions. Vulnerability research has been an important foundation in urban risk management. To make cities safe and resilient, it is also necessary to integrate the connection among cities into a vulnerability assessment. Therefore, this paper proposed a new conceptual framework for urban social vulnerability assessment based on network theory, where a new dimension of social vulnerability (connectivity) was added into the framework. Using attribute data, the traditional social vulnerability index of a city (SVI node ) was calculated via the projection pursuit cluster (PPC) model. With the relational data retrieved from the Baidu search index, a new dimension (connectivity) of social vulnerability (SVI connectivity ) was evaluated. Finally, an integrated social vulnerability index (SVI urban ) was measured combined with SVI node and SVI connectivity . This method was applied in the Yangtze River Delta region of China, where the top three high values of SVI node belonged to the cities of Taizhou (Z), Jiaxing, and Huzhou. The three lowest cities were Hangzhou, Nanjing, and Shanghai. For SVI urban , the social vulnerability of cities in different hierarchies behaved differently. For Hierarchies 2 and 3, when compared to SVI node , the SVI urban was significantly reduced. However, the variation between SVI node and SVI urban in Hierarchy 4 was slight. Furthermore, an increase for the city of Taizhou (J) in its social vulnerability was achieved after connecting to the network. Huzhou, in Hierarchy 5, increased its social vulnerability the most when adding connectivity in the social vulnerability assessment. Based on the results of our case study, a conclusion was drawn that network connectivity had an influence on social vulnerability. However, when connectivity was strong enough, it could help cities to mitigate their traditional social vulnerability, whereas a loose connection in the network aggregated their traditional social vulnerability. Hence, the latter should be emphasized in future urban risk management.