The corrosion behaviors of 1420 Al-Li alloy under 4 ml MgCl 2 drops with initial concentration of 0.1-1.0 M in relative humidity (RH) 33% were studied using a Kelvin Probe. In all cases, the equilibrium MgCl 2 concentration was 4.9 M. The corrosion was highly dependent on the initial MgCl 2 concentration. After equilibration with the environment RH, the whole available cathodic limiting current associated with oxygen reduction was decreased with increasing the initial MgCl 2 concentration. Accordingly, the corrosion rate was decreased. Under the MgCl 2 drops with initial 0.1 and 0.3 M concentrations, the main corrosion form was filiform-like corrosion. While, as the initial concentration was increased to 1.0 M, the main corrosion form was meta-stable pitting corrosion. In the case of 0.1 and 0.3 M initial concentrations, along the Volta potential baseline at À0.7 to À0.8 V SHE , there existed many potential transients in the form of rapid increase followed by immediate drop, which should be associated with the filiform-like corrosion growth stop and initiation. In the case of 1.0 M initial concentration, much more potential transients appeared in the form of sudden drop followed by a recovery, which was associated with the initiation and re-passivation of meta-stable pits.