Potentiometric investigation of dialuminum heptachloride formation in aluminum chloride-1-butylpyridinium chloride mixtures

Abstract

constrained to be 0.7, a value which would admit some covalency in the chromium-carborane bonds. The resulting best fit, which yielded a value for the distortion parameter of 555 cm'1, is shown in Figure 6, where it may be seen that the fit is not good, even qualitatively. These data suggest that the chromium(II) carborane complex and chromocene have comparable electronic ground states, but it is clear that a structural study of the former is needed before a definitive answer can be had for this problem.

An Electrochemical and Infrared Study of Chloranil in n‐Butylpyridinium Chloride:Aluminum Chloride Ionic Liquid

“…Recent work has shown that AICl 3 complexation of such species as aromatic hydrocarbons, 5 aromatic amines, 4 and 6 9,10-anthraquinone occurs in the acidic melt, the results indicating that the existence of AICI 3 in this system as Al 2 Cl does not prevent its interaction with basic centers on the molecules studied. 6 Since considerable work has been carried out in the high-temperature AIC1 3 :NaCl system, 7 -11 it is of interest to relate the properties of these AICI 3 -based molten salt systems by studying a particular solute in both systems.…”

Oxidation of Nickel in AlCl3-1-Butylpyridinium Chloride at Ambient Temperature

“…Prominent anodic peaks appeared at 0.4 and 0.5 V vs. Al/Al 3+ and the peak at around 1.1 V disappeared. This is thought to be the main reason why the EMF value of each electrode changed with the change in molar ratio of the AlCl 3 /BPC salt 15 and the change in EMF varies according to each electrode material. 15,16 Anodic current in Fig.…”

“…[15][16][17][18][19][20][21][22][23][24][25][26][27][28][29] Such chloroaluminate salts vary their melting points, decreasing to lower temperature as they approach, by changing the ratio of AlCl 3 and organic salts, although their ion conductivity has been reported to be well maintained. Accordingly, many studies have been done on electrochemical properties for chloroaluminate salts with organic salts at around 100…”

Dialkylimidazolium Chlorides

“…Mixtures of l-alkylpyridinium halides and aluminum chloride have been shown to be molten at room temperature (5) , and are useful as electrolytes in electrochemical cells (6,7). Furthermore, the alkylpyridinium chloroaliminates were shown to be suitable as battery electrolytes (8).…”