1957
DOI: 10.1016/s0003-2670(00)89953-5
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Potentiometric titrations in non-aqueous solution

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Cited by 53 publications
(8 citation statements)
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“…Presumably the methanol in the solvent mixture constitutes an excess sufficient to cause predominant amphiprotic solvent characteristics. Van der Heijde and Dahmen (17), working in the 0.01 7 range, observed that the apparent purity of uncharged oxygen acids in amphiprotic solvents was enormously enhanced.…”
Section: A Direct Quantitative Comparison Between Results In Differen...mentioning
confidence: 99%
“…Presumably the methanol in the solvent mixture constitutes an excess sufficient to cause predominant amphiprotic solvent characteristics. Van der Heijde and Dahmen (17), working in the 0.01 7 range, observed that the apparent purity of uncharged oxygen acids in amphiprotic solvents was enormously enhanced.…”
Section: A Direct Quantitative Comparison Between Results In Differen...mentioning
confidence: 99%
“…[2][3][4][5][6] The presented procedures for the evaluation of the E s scale were based on the determination the difference between the half-neutralization potentials of perchloric acid and tetraethylammonium hydroxide (TEAH) or tetrabutylammonium hydroxide (TBAH) in the given solvent. [2][3][4][5][6] The presented procedures for the evaluation of the E s scale were based on the determination the difference between the half-neutralization potentials of perchloric acid and tetraethylammonium hydroxide (TEAH) or tetrabutylammonium hydroxide (TBAH) in the given solvent.…”
Section: Introductionmentioning
confidence: 99%
“…Organic bases in nitromethane have been studied and a linear relationship between the relative strength of these bases in nitromethane and water was found (7). The factors that may influence the half-neutralization potential of acids and bases in different solvents have been outlined (8). In all these investigations, a straight-line relationship was noted between the relative strengths of acids in water and in nonaqueous media.…”
mentioning
confidence: 99%