The experimental observations of the photoelectric effect show the properties of quantum mechanics of the electromagnetic field. For this reason, this important effect is commonly used as an introductory topic for the study of quantum physics. The “classical” demonstration of the photoelectric effect is very incisive; unfortunately, the experimental apparatus is not cheap and easy to realize. The typical use of LEDs is as light emitters, but they can be used even as photosensors and, in this case, they are sensitive to wavelengths equal to or shorter than the predominant wavelength it emits. Furthermore, a LED used as detector is sensitive to wavelengths equal to or shorter than the predominant wavelength it emits. This ability of LEDs offers the possibility of developing a simple tool able to demonstrate the photoelectric effect. This paper describes the realization of an economic, simple, easy and safe system to use for the experimental demonstration of the photoelectric effect, based on the LED to LED structure. The paper has educational purposes, oriented towards laboratory teaching activities.