This study investigates the feasibility of ambient radio frequency (RF) energy harvesting for powering low-power electronic devices, in domestic environments. An RF spectrum survey was carried out in a variety of locations around the city of Bristol, UK between 500 MHz and 6 GHz. Locations are limited to indoor residential environments, and as a comparison an office. The measurement setup consists of an omnidirectional, broadband, discone antenna and a handheld spectrum analyser. On the basis of the measured power consumption of a number of low-power electronic devices and the analysed results, the required harvesting time to power each device is calculated. The results show that in order to harvest enough energy to power-up a small calculator (2 μW) for 1 s, an antenna array covering 1.7-2.5 GHz with effective area of 1 m 2 requires on average about 10 min of harvesting.