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Cited by 3 publications
(3 citation statements)
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“…Quite recently, a new peroxo complex, namely, the calcium peroxide diperoxohydrate (CaO 2 × 2H 2 O 2 ), has been reported to produce the 1270-nm emission of 1 O 2 (yield is 25%) upon decomposition. The IR−CL emission of singlet oxygen at 1270 nm was also detected in the V 5+ -catalyzed decomposition of H 2 O 2 in acetic acid, presumably through the intermediary diperoxo species. Similarly, singlet-oxygen infrared CL was produced in the catalyzed disproportionation of hydrogen peroxide by lanthanum(III) ions under heterogeneous conditions …”
Section: 2 Hydrogen Peroxidementioning
confidence: 91%
“…Quite recently, a new peroxo complex, namely, the calcium peroxide diperoxohydrate (CaO 2 × 2H 2 O 2 ), has been reported to produce the 1270-nm emission of 1 O 2 (yield is 25%) upon decomposition. The IR−CL emission of singlet oxygen at 1270 nm was also detected in the V 5+ -catalyzed decomposition of H 2 O 2 in acetic acid, presumably through the intermediary diperoxo species. Similarly, singlet-oxygen infrared CL was produced in the catalyzed disproportionation of hydrogen peroxide by lanthanum(III) ions under heterogeneous conditions …”
Section: 2 Hydrogen Peroxidementioning
confidence: 91%
“…Ozone formation 15 2. Evolution of singlet dioxygen upon H 2 O 2 decomposition 14 3. Ability of peroxo complexes to hydroxylate alkanes with cleavage of a C-H bond.…”
Section: Possible Reactive Intermediates Of Hydroperoxide Oxidation Imentioning
confidence: 99%
“…Our experiments have shown that this system can cleave C-C and C-H bonds in alkanes, 10 the C=C bond in alkenes, 11 transfer a singlet dioxygen molecule to substrates capable of diene synthesis 12 and oxidise molecular nitrogen. 13 Furthermore, O 2 ( 1 Δ g ) 14 and ozone 15 are generated in the system (Scheme 1).…”
mentioning
confidence: 99%