Precisely tailored LaFeO<sub>3</sub>dendrites using urea and piperazine hexahydrate for the highly selective and sensitive detection of trace level acetone

Thiruppathi, K. Palani; Nataraj, D.

doi:10.1039/d0ma00602e

Cited by 8 publications

(1 citation statement)

References 45 publications

(74 reference statements)

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“…In the LFO@NCA spectra, the peak of −C–F– is detected, whereas the in bare NCA, the PVDF peak is not distinguished. This indicates that the parasitic reaction-induced electrolyte decomposition, which is directly related to the HF concentration in the electrolyte, is inhibited in the LFO-coated cell. − …”

Section: Resultsmentioning

confidence: 99%

Parasitic Reaction Alleviation of Ni-Rich Cathode Active Materials at Elevated Temperatures Using a Perovskite-Type Lanthanum Iron Oxide

Kim

Shaji

Nanthagopal

et al. 2023

ACS Appl. Energy Mater.

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Lithium-ion batteries (LIBs) are dominantly used as energy storage systems for mobile devices and electric vehicles. Ni-rich Li[Ni x Co y Al 1-x-y ]O 2 (NCA) is considered a promising cathode material for the next-generation LIBs because of its high theoretical capacity. However, Ni-rich cathodes are operated strictly within a limited temperature range to avoid thermal runaway. At elevated temperatures, their structural stability is damaged, inducing severe capacity fading. In this study, we used a simple wet chemical synthesis technique to coat an NCA cathode material with a perovskite-type LFO. The resulting LFO-coated NCA cathode material exhibited improved electrochemical properties and enhanced structural stability at high temperatures. Our electrochemical performance revealed that the LFO-coated NCA cathode material exhibits higher initial discharge capacity and better capacity retention after cycling than bare NCA, especially at elevated temperatures and higher C-rates. Furthermore, our results suggest that the LFO coating layer effectively protects the active cathode material from the parasitic reaction during cycling, which can cause capacity fading. The protective layer formed by the LFO coating inhibits the reaction between the active material and the electrolyte, thereby preserving the structural integrity and electrochemical performance of the cathode material. These findings provide insight into the development of the next-generation LIBs that can operate at higher temperatures and have better electrochemical performance.

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Section: Resultsmentioning

confidence: 99%

Parasitic Reaction Alleviation of Ni-Rich Cathode Active Materials at Elevated Temperatures Using a Perovskite-Type Lanthanum Iron Oxide

Kim

Shaji

Nanthagopal

et al. 2023

ACS Appl. Energy Mater.

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Comparative Analysis of Nanostructures Formed by the Chemical Route in the Ferrum–Lanthanum-Containing Systems

Lavrynenko,

Pavlenko,

Olifan

2023

Springer Proceedings in Physics

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Electrochemical assessment of tailored Mn2O3 cuboidal hierarchical particles prepared using urea and Piperazine

Dhakal,

Perez,

Mishra

2024

Electrochimica Acta

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Precisely tailored LaFeO₃dendrites using urea and piperazine hexahydrate for the highly selective and sensitive detection of trace level acetone

Abstract: A highly selective and sensitive detection of trace (10 ppb) level acetone sensing device was fabricated using precisely tailored LaFeO3 dendrites.

Cited by 8 publications

References 45 publications

Parasitic Reaction Alleviation of Ni-Rich Cathode Active Materials at Elevated Temperatures Using a Perovskite-Type Lanthanum Iron Oxide

Parasitic Reaction Alleviation of Ni-Rich Cathode Active Materials at Elevated Temperatures Using a Perovskite-Type Lanthanum Iron Oxide

Comparative Analysis of Nanostructures Formed by the Chemical Route in the Ferrum–Lanthanum-Containing Systems

Electrochemical assessment of tailored Mn2O3 cuboidal hierarchical particles prepared using urea and Piperazine

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Precisely tailored LaFeO3dendrites using urea and piperazine hexahydrate for the highly selective and sensitive detection of trace level acetone

Abstract: A highly selective and sensitive detection of trace (10 ppb) level acetone sensing device was fabricated using precisely tailored LaFeO3 dendrites.

Cited by 8 publications

References 45 publications

Parasitic Reaction Alleviation of Ni-Rich Cathode Active Materials at Elevated Temperatures Using a Perovskite-Type Lanthanum Iron Oxide

Parasitic Reaction Alleviation of Ni-Rich Cathode Active Materials at Elevated Temperatures Using a Perovskite-Type Lanthanum Iron Oxide

Comparative Analysis of Nanostructures Formed by the Chemical Route in the Ferrum–Lanthanum-Containing Systems

Electrochemical assessment of tailored Mn2O3 cuboidal hierarchical particles prepared using urea and Piperazine

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Precisely tailored LaFeO₃dendrites using urea and piperazine hexahydrate for the highly selective and sensitive detection of trace level acetone