Precision Macroporous Monoliths Made Using High‐Throughput Microfluidic Emulsification

Abstract

Materials with pore sizes ranging from micrometers to millimeters find use in thermal insulation, acoustics, separation, and energy‐related applications. While several routes have been developed to manufacture such macroporous materials, current fabrication technologies remain limited in either scalability or pore size control. Herein, a scalable microfluidic approach is reported to create macroporous materials with precisely controlled pore sizes from monodisperse emulsion templates. Emulsion droplets produced in a parallelized step emulsification device are assembled by gravity and converted into macroporous monoliths by polymerization and drying. Microstructural analysis and model filtration experiments show that the pore windows of the bulk macroporous material can be tightly controlled and used for the size‐selective separation of particles from suspensions. By heat treating macroporous structures of selected compositions, one can also create bulk carbon and silica glass monoliths with unique cellular architectures for potential applications as filters, separation membranes, or catalyst supports.