2015
DOI: 10.1039/c4ay03114h
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Preconcentration of ultra-trace Cu(ii) and Cd(ii) using SPE based on an alizarin complexone modified silica gel with detection using FAAS and determination of ultra-trace Cu(ii) by the naked eye

Abstract: By the gradient elution of Cu(II) and Cd(II), enriched Cu(II) could be completely separated from Cd(II) and monitored with the naked eye using color agent 5-Br-PADAP.

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Cited by 7 publications
(3 citation statements)
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“…Dihydroxyanthraquinone (DHAQs) dyes which bearing O-H and C=O moieties and composed a well-known family of dye compounds. Alizarin derivatives constitute an interesting family of anthraquinone dyes and used for determination of metal ions [1][2][3][4] and molecules [5][6][7][8] determination and in textile industry. 9,10 Among them, alizarin red-S dye is extensively employed in textile industry due to their wide range of color shades (yellow to purple) and ease of application.…”
mentioning
confidence: 99%
“…Dihydroxyanthraquinone (DHAQs) dyes which bearing O-H and C=O moieties and composed a well-known family of dye compounds. Alizarin derivatives constitute an interesting family of anthraquinone dyes and used for determination of metal ions [1][2][3][4] and molecules [5][6][7][8] determination and in textile industry. 9,10 Among them, alizarin red-S dye is extensively employed in textile industry due to their wide range of color shades (yellow to purple) and ease of application.…”
mentioning
confidence: 99%
“…In FT-IR spectrum of Al 2 O 3 -PB-AC new peaks are observed at 1420 cm −1 and 1350 cm −1 (bending vibrations of -C-N-H-), 1620 cm −1 (stretching vibrations of -N-C = C-O-), 2850 cm −1 and 2910 cm −1 that can be attributed to the saturated -C-H groups [41,42]. Appearance of these frequency bands in FT-IR spectrum of Al 2 O 3 -PB-AC provides fixation of AC on the surface of Al 2 O 3 -PB.…”
Section: Characterisation Of the Al 2 O 3 -Pb-ac Adsorbentmentioning
confidence: 99%
“…Commercially available 3‐[ N , N ‐bis(carboxymethyl)‐aminomethyl]‐1,2‐dihydroxyanthraquinone [alizarin complexone (ALC)] has one amino, two carboxylate, two carbonyl, and two hydroxyl groups that can form a chelate complex with metal ions (Scheme ). It has been demonstrated that ALC is a useful water‐soluble chromogenic chelating reagent for the spectrophotometric determination of metals such as Al 3+ , Ce 3+ , Cu 2+ , and Gd 3+ In addition, the ALC and La 3+ complex has been utilized as a photometric reagent for fluoride ion …”
Section: Introductionmentioning
confidence: 99%