Human hearing adapts to steady signals, but remains very sensitive to fluctuations as well as to prominent, salient noise events. The higher these fluctuations are, the more annoying a sound is possibly perceived. To quantify these fluctuations, descriptors have been proposed in the literature and, among these, the intermittency ratio (IR) has been formulated to quantify the eventfulness of an exposure from transportation noise. This paper deals with the application of IR to urban road traffic noise data, collected in terms of 1 s A-weighted sound pressure level (SPL), without being attended, monitored continuously for 24 h in 90 sites in the city of Milan. IR was computed on each hourly data of the 251 time series available (lasting 24 h each), including different types of roads, from motorways to local roads with low traffic flow. The obtained hourly IR values have been processed by clustering methods to extract the most significant temporal pattern features of IR in order to figure out a criterion to classify the urban sites taking into account road traffic noise events, which potentially increase annoyance. Two clusters have been obtained and a “non-acoustic” parameter x, determined by combination of the traffic flow rate in three hourly intervals, has allowed to associate each site with the cluster membership. The described methodology could be fruitfully applied on road traffic noise data in other cities. Moreover, to have a more detailed characterization of noise exposure, IR, describing SPL short-term temporal variations, has proved to be a useful supplementary metric accompanying LAeq, which is limited to measure the energy content of the noise exposure.