Predicting the approximate solubilities of solids in dense carbon dioxide

Solubility Prediction in Supercritical CO2 Using Minimum Number of Experiments

“…3 produced the least accurate results, with 24.8%. It is suggested that percentage errors < 20% are acceptable because the produced correlation error for equations of state (which are used in chemical engineering calculations) is ∼20% 12. The global AARD for eq.…”

“…Hutchenson and Foster10 reported deviations between experimental and calculated solubilities using the PR equation of state11 of > 50% for naphthalene solubility data in SC CO 2 . Trablesi and co‐workers12 employed the PR and Bublik–Mansoori equations of state13,14 to correlate α‐ and β‐naphthol solubility data in SC CO 2 and showed that both equations produced an average absolute relative deviation (AARD) of ∼21%. The authors also assessed the correlation ability of the Bublik–Mansoori equation of state using 13 solubility data sets of different compounds in SC CO 2 , which resulted in an AARD of 22.6%.…”

“…The authors also assessed the correlation ability of the Bublik–Mansoori equation of state using 13 solubility data sets of different compounds in SC CO 2 , which resulted in an AARD of 22.6%. To provide a predictive equation, an average value of solute–solvent interaction parameter ( a 12 ) was used for nine compounds, which possess a solubility of < 10 −3 mole fraction and high AARD of ∼40% 12. The a 12 parameter is calculated using all experimental points in each data set by an iteration method.…”

Thermodynamic Data for Processing Naphthol with Supercritical Carbon Dioxide

“…Naphthol as a solid compound has been interesting for experimental and theoretical studies for many years. − Even if solubility models of different compounds in supercritical fluids exist, the experimental data are the most valuable information for designing processes of producing naphthol with a defined size and shape with supercritical fluids. Therefore, solubility measurements of 1-naphthol , and derivates of 1-naphthol in CO 2 were performed.…”

Estimation of solid vapor pressures of pure compounds at different temperatures using a multilayer network with particle swarm algorithm

“…To directly estimate P S , extrapolation of Antoine type equations have been used by Iwai et al [11] and by Trabelsi et al [12], while enthalpy data and melting temperature with the Lee-Kesler equation have been employed by Nanping et al [13]. Goodman et al [10] obtained H S from functional groups and molecular parameters.…”