2010
DOI: 10.1002/aic.12232
|View full text |Cite
|
Sign up to set email alerts
|

Predicting the phase equilibria of synthetic petroleum fluids with the PPR78 approach

Abstract: The PPR78 approach is a group contribution-based thermodynamic model which combines at constant packing fraction the Peng-Robinson equation of state and a Van Laar-type g E model. This article demonstrates that, using classical mixing rules (linear on b and quadratic on a), the PPR78 model may also be seen as a group contribution method for the estimation of the temperature-dependent k ij of the widely used PR EoS. Our model is endowed of 15 groups and it is possible to predict the k ij for any mixture contain… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1
1

Citation Types

1
113
0

Year Published

2011
2011
2018
2018

Publication Types

Select...
7
1
1

Relationship

1
8

Authors

Journals

citations
Cited by 168 publications
(114 citation statements)
references
References 65 publications
1
113
0
Order By: Relevance
“…The capability of the PPR78 model is now illustrated in such mixtures. All the references of the experimental datapoints can be found in [12]. [12]).…”
Section: Predicting the Phase Behavior Of Co 2 -Containing Multicompomentioning
confidence: 99%
See 1 more Smart Citation
“…The capability of the PPR78 model is now illustrated in such mixtures. All the references of the experimental datapoints can be found in [12]. [12]).…”
Section: Predicting the Phase Behavior Of Co 2 -Containing Multicompomentioning
confidence: 99%
“…In the current state, the PPR78 model can cover a large spectrum of petroleum fluids, from natural gases to crude oils [3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18]. 20 groups exist and make it possible to accurately predict the phase behavior of mixtures containing alkanes, alkenes, aromatic compounds, cycloalkanes, permanent gases (CO 2 …”
Section: The Equation Of State (Eos)mentioning
confidence: 99%
“…The group-contribution (GC) approach is a relatively recent concept [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17] which originally aimed at predicting the physical properties of pure molecules starting from their chemical structures. The application of the GC concept to mixtures is actually an extension of the GC concept for single molecules [3,18].…”
Section: General Aspectsmentioning
confidence: 99%
“…Normally, the NGL in the tank is a saturated liquid [6]. Once the pressure drops down to the saturation vapor pressure of the NGL during the leakage process, the NGL would evaporate, causing the coexistence of liquid and vapor phases in the tank and the leak hole [7,8]. …”
Section: Introductionmentioning
confidence: 99%