An approach for improving the identification and discrimination ability of an electronic tongue multi-sensor array was developed. The detail signal was obtained by decomposing the original voltammetric signal using wavelet packet decomposition, and the feature value was extracted by fast Fourier transform with the influence of collinearity eliminated. Based on the principle of information entropy, the sensing entropy of a single electrode and between electrodes in the multi-sensor array were defined, and the unit sensing vector and interactive sensing vector were constructed. The results showed that six unit sensing entropies could be effectively used for the identification of rice origin, and all interactive sensing vectors for the discrimination of rice type. SVM and KNN classifiers were employed. The results showed that the training and prediction accuracy of SVM with interactive sensing vector as the input for identifying rice origin were 89.0% and 82.9%, respectively, and that for distinguishing rice type were 96.0% and 88.6%, respectively. In conclusion, the SVM model with interactive sensing vector could be an approach to accurately identify rice origin and type. The identification and discrimination ability of multi-sensor array could be enhanced by using the sensing interaction information based on information entropy.