The relationship between stress and strain for polypropylene film was studied under strain rates from 0.13 to 5.21 s 21 in order to study the deformation behavior of film under higher strain rates than previous studies. Uniform thickness was obtained in the strain rates from 2.08 to 5.21 s 21 at 435 K, or from 2.08 to 3.13 s 21 at 437 K. The temperature rise of film due to the generation of heat from plastic strain influenced the relationship between stress and strain, in particular, at high strain rates and low temperature. Material constants for the constitutive equation of film were determined using the measurements from 2.08 to 5.21 s 21 at 435 K and from 2.08 to 3.13 s 21 at 437 K. Film thicknesses during and after transverse direction stretching were successfully predicted by applying the material constants obtained. The authors concluded that the material constants should be determined by applying the stretching conditions, under which there is little or no effect from heat generation and under which film can be stretched uniformly in thickness. POLYM. ENG. SCI., 53:309-320, 2013. ª