The aim of the work is to develop and test for specific conditions of the blast furnace algorithmic means of the Expert system for selecting the optimal composition of the multicomponent charge, which provides the necessary technical and economic indicators of melting in variable raw material and energy conditions. The features of algorithmic means of the system for selecting the optimal composition of blast furnace charge, which are developed using methods of physicochemical and mathematical modeling of the processes of distribution and melting of iron ore materials in different zones of the furnace for the development of scientifically based recommendations for adjusting the composition of the charge, taking into account the available raw materials and energy resources. The system implements a set of physicochemical models and criteria for describing the processes of distribution of iron ore materials along the blast furnace radius, their phase transformations in high-temperature zones and directed formation of melts, which are regulated by a system of reasonable technological constraints. The information basis for the creation of predictive models for calculating the physical and chemical properties of metallurgical melts is the information accumulated in the databases "Iron ore materials", "Slag" and "Metal-slag" created in the Institute of Ferrous Metallurgy of the integrated Knowledge Base "Metallurgy". The solution of the optimization problem is carried out on the basis of expert evaluation of the forecasting of melting indicators and calculation of the optimal composition of the charge using vector optimization methods by finding a compromise between the accepted optimality criteria and technological constraints. The Expert system has been tested and recommendations on the component composition of blast charge for specific blast furnace operating conditions have been developed.