Prediction of decline in shale gas well production using stable carbon isotope technique

Zhao, Shengxian; Kang, Shugang; Zheng, Majia; Lu, Shuangfang; Yang, Yibo; Zhang, Huanxu; Liu, Yansheng; Xia, Ziqiang; Zhang, Chenglin; Hu, Haoran; Zhu, Di

doi:10.1007/s11707-021-0935-4

Cited by 4 publications

(1 citation statement)

References 39 publications

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“…To date, many studies have been carried out to investigate the mechanisms for the carbon isotopic characteristics of shale gases (Ferworn et al, 2008;Burruss and Laughrey, 2010;Rodriguez and Philp, 2010;Zumberge et al, 2012;Hao and Zou, 2013;Xia et al, 2013;Gao et al, 2014;Zhang et al, 2018b;Xia and Gao, 2018;Feng et al, 2020;Mi et al, 2022). Moreover, isotopic reversal may correlate with the gas generation potential, and the reversal magnitude may correspond to the amount of gas retained in the shale (Tilley et al, 2011;Feng et al, 2018;Wang et al, 2021;Zhao et al, 2021).…”

Section: Introductionmentioning

confidence: 99%

Geochemical Characteristics and Origin of Shale Gases From Sichuan Basin, China

Dong

Yao

et al. 2022

Front. Earth Sci.

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Natural gases from the Taiyang (shallow), Jiaoshiba (middle), and Weirong (deep) shale gas fields in the southern Sichuan Basin were analyzed for molecular and stable carbon isotopic compositions to investigate the geochemical characteristics and gas origins. All the gases belong to shale gas from the Upper Ordovician–Lower Silurian shale and are dominated by methane with gas wetness generally less than 0.83%. The δ13C1 values are −28.5‰, −30.3‰, and −35.2‰ in Taiyang, Jiaoshiba, and Weirong shale gas fields, respectively. The extremely high thermal maturity is the controlling factor for the enrichment of 13C in methane, with a minor contribution from the heavy carbon isotope of the organic matter in the Ordovician Wufeng Formation. Fischer–Tropsch-type synthesis of hydrocarbon gas from CO2 and H2 contributes to the increase of wet gas, which results in the offset from the δ13C1∼wetness linear trend in the Taiyang and Jiaoshiba gas fields. Methane, ethane, and propane in the Taiyang shale gas field have increasing δ13C values with increasing burial depth, which is mainly caused by diffusive migration. All gases are characterized by a complete carbon isotopic reversal trend (δ13C1 > δ13C2 > δ13C3), and it is mainly caused by the reversible free-radical reactions with the conversion from alkane to alkyl groups, with some contribution from the Fischer–Tropsch-type synthesis. The results of this study will improve our understanding of the geochemical characteristics of shale gases from different burial depths and have important implications for future shale gas exploration in the deep and shallow layers.

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