2017
DOI: 10.1002/app.45942
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Prediction of plasticity‐controlled failure in polyamide 6: Influence of temperature and relative humidity

Abstract: In this study, the influence of temperature and relative humidity on the plasticity controlled failure of polyamide 6 was investigated. Uniaxial tensile tests were performed at several temperatures, strain rates, and relative humidity; creep tests were performed at different relative humidity and applied load. In order to describe and predict the yield kinetics, the Ree–Eyring equation was employed and modified to include the effect of relative humidity. Subsequently, by the introduction of the concept of crit… Show more

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Cited by 42 publications
(52 citation statements)
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“…This is evident by looking at the results shown in Fig. 14b: according to models that link the mechanical response of a polymeric material to the temperature distance from T g [131], we should have obtained the same response for the two cases illustrated. Such a discrepancy might depend on the different microstructures of the materials cured at various light intensities (an in-depth discussion on this aspect can be found in ''Discussion'' section), pointing at the limitations of predicting the mechanical behaviour through approaches that neglect the role of the microstructure on the photopolymerisation process.…”
Section: Pointwise Mechanistic Kinetic Modelmentioning
confidence: 79%
“…This is evident by looking at the results shown in Fig. 14b: according to models that link the mechanical response of a polymeric material to the temperature distance from T g [131], we should have obtained the same response for the two cases illustrated. Such a discrepancy might depend on the different microstructures of the materials cured at various light intensities (an in-depth discussion on this aspect can be found in ''Discussion'' section), pointing at the limitations of predicting the mechanical behaviour through approaches that neglect the role of the microstructure on the photopolymerisation process.…”
Section: Pointwise Mechanistic Kinetic Modelmentioning
confidence: 79%
“…Effectively, humidity and temperature act equivalently in PA6, as at constant temperature the environmental humidity level induces a glass-to-rubber transition. 44,45 In contrast, in the LCN the moduli remain quite stable to changes of humidity; no T g was detected from the tan d versus relative humidity plot. Still, humidity does appear to influence the LCN (Fig.…”
Section: Singe Layersmentioning
confidence: 91%
“…Each deformation process is described with a rate factor _ ε 0,i dependent on the thermodynamic state of the material, an activation energy ΔU i , and an activation volume V * i , R is the universal gas constant, T is the temperature, and k is Boltzmann's constant. The same approach has been already successfully applied to many other polymers such as iPP, 19 PA6, 20 PMMA, 21 and PC. 22 To predict lifetime, we made use of the observation that, in creep experiments, the product of time to failure and the plastic flow rate during secondary creep is constant and this constant can be regarded as a critical accumulated strain 23 :…”
Section: Introductionmentioning
confidence: 94%
“…Equation 4was shown to be very effective in predicting the influence of humidity and temperature on the deformation kinetics of PA6. 20 The apparent temperature is based on the hypothesis that the mechanical response at any temperature is determined by the difference between the testing temperature and the glass transition temperature. Absorbed water results in a depression of the glass transition temperature, which can be regarded as an "apparent" increase in the ambient temperature.…”
Section: Introductionmentioning
confidence: 99%