Ozone pollution is harmful to human health and ecosystem, which occurs in ecosystems and has occurred frequently in China in recent years, especially during the warm seasons.Meteorological conditions are among the important factors affecting the occurrence of ozone pollution. In this study, a classification method for meteorological conditions of ozone pollution levels based on a back propagation (BP) neural network was proposed to reflect the impact of meteorological conditions on the occurrence of ozone pollution. Ozone pollution was divided into three levels according to surface hourly ozone (O3) concentrations and thus into three groups of meteorological conditions. The input physical parameters for the BP neural network were determined by evaluating the relationship between surface O3 concentrations and meteorological parameters and precursors, including relative humidity, temperature, mixing layer height, precipitation, and nitrogen dioxide (NO2) concentrations. The study area focused on 21 cities in Sichuan Province in southwestern China, which was divided into 12 BP classifiers according to the urban geographical location and sample number of each city, and a single BP classifier was trained for 21 cities. The classification results of the trained BP classifiers were verified by comparison to the observations. With 12 individual BP classifiers, the classification accuracy of all 21 cities was more than 60%, of which 18 cities were more than 70%, and 9 cities were more than 80%. With the single BP classifier, the classification accuracy of 20 cities was more than 60%, of which 18 cities were more than 70%, and 14 cities were more than 80%. Overall, the classification performance of the trained single model was better than trained 12 individual models. The classification method can comprehensively reflect the impact of meteorological conditions on the occurrence of ozone pollution.