For manufacturing components with thick plates, such as in the heavy equipment and shipbuilding industries, the gas metal arc welding (GMAW) process is applied. Among the components that apply the thick plate GMAW process, there are groove butt joints, which are fabricated through multi-pass welding. Various welding qualities are managed in multi-pass welding, and the root-pass weld is controlled to ensure complete joint penetration (CJP). Currently, the state of complete joint penetration during root-pass welding is managed visually, making it difficult to confirm the penetration condition in real time. Therefore, there is a need to predict the penetration condition in real time. In this study, we propose a convolutional neural network (CNN)-based prediction model that can classify penetration conditions using welding current and voltage data from the root pass of V-groove butt joints. The root gap of the joints was varied between 1.0 and 2.0 mm, and the wire feed rate was adjusted. During welding, the current and voltage were measured. The welding current and voltage are transformed into a short-time Fourier transform (STFT) representation depicting the arc and wire extension lengths. The transformed dynamic resistance STFT information serves as the input variable for the CNN model. Preprocessing steps, including thresholding, are applied to optimize the input variables. The CNN architecture comprises three convolutional layers and two pooling layers. The model classifies penetration conditions as partial joint penetration (PJP), CJP, and burn-through, achieving a high accuracy of 97.8%. The proposed method facilitates the non-destructive evaluation of the root-pass welding quality without expensive monitoring equipment, such as vision cameras. It is expected to be immediately applied to the thick plate welding process using readily available welding data.