Preferential adsorption in a near-critical binary fluid mixture as analyzed in the framework of the non-random two-liquid model

Fujitani, Youhei

doi:10.1016/j.fluid.2024.114050

Fluid Phase Equilibria

2024

DOI: 10.1016/j.fluid.2024.114050

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Preferential adsorption in a near-critical binary fluid mixture as analyzed in the framework of the non-random two-liquid model

Youhei Fujitani

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2024

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Cited by 2 publications

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Force density induced by preferential adsorption in a near-critical binary fluid mixture subject to the Soret effect

Fujitani

2024

The Journal of Chemical Physics

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We assume that two parallel plates are immersed in a binary fluid mixture lying in the one-phase region near the demixing critical point and that the surface of each plate attracts the mixture components differently via short-range interactions. It is known that the composition inhomogeneity caused by the difference can induce a force exerted on the plate at equilibrium. In the present study, we investigate how a temperature gradient imposed vertically on the plates changes the induced force by calculating the composition profile subject to the Soret effect. Numerically solving the derived differential equation, we show that a temperature gradient within the critical regime can change the force distinctly from its equilibrium value and can make the force direction opposite to the one at equilibrium.

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Force density induced by preferential adsorption in a near-critical binary fluid mixture subject to the Soret effect

Fujitani

2024

The Journal of Chemical Physics

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Thermo-osmosis of a near-critical binary fluid mixture: A general formulation and universal flow direction

Yabunaka,

Fujitani

2024

Phys. Rev. E

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Preferential adsorption in a near-critical binary fluid mixture as analyzed in the framework of the non-random two-liquid model

Cited by 2 publications

References 77 publications

Force density induced by preferential adsorption in a near-critical binary fluid mixture subject to the Soret effect

Force density induced by preferential adsorption in a near-critical binary fluid mixture subject to the Soret effect

Thermo-osmosis of a near-critical binary fluid mixture: A general formulation and universal flow direction

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