“…To describe such non-equilibrium of water flow and solute transport in soils, many numerical models have been recently developed. Overviews of non-equilibrium water flow and solute transport evidence, and various experimental and mathematical approaches to study and describe these phenomena were given by Šimůnek et al (2003), Gerke (2006), Jarvis (2007), Clothier et al (2008), Šimůnek et al (2008a), Šimůnek and van Genuchten (2008), or Köhne et al (2009a, b). Common physically based models for simulation of water flow and solute transport in structured soils assume (one) continuum and bi-or multi-continuum approaches.…”