Accreting skeletal tissues found in bone, teeth, otoliths and molluscan shell act as sensitive recorders of local environmental and climatic conditions. Owing to their robust nature, ubiquity and abundance in the archaeological record as well as the potential for high-resolution data acquisition, the accreting skeletal tissues of archaeological molluscs are increasingly employed as palaeoenvironmental proxies. Researchers have chiefly utilised such proxies to extend instrumental records of environmental conditions through palaeoenvironmental reconstruction and explore the impact of environmental and climatic change on human populations. However, the use of environmental proxies from the archaeological record can be hampered by a number of methodological challenges including inadequate sampling strategies, appropriate calibration, the use of inappropriate proxies and the broad extrapolation of localised results. This paper reviews the use of molluscan shell from archaeological contexts as palaeoenvironmental proxies. We focus on the application of sclerochronology-a suite of high-resolution physical and geochemical data recovery methods widely used in conjunction with molluscan shell. This paper presents an overview of the potential of these techniques in approaching more nuanced understandings of human-environment interactions and how they can be more successfully incorporated into archaeological research.