Space
cooling and heating consume a large proportion of global
energy, so passive thermal management materials (i.e., without energy
input), especially dual-mode materials including cooling and heating
bifunctions, are becoming more and more attractive in many areas.
Herein, a function-switchable Janus membrane between cooling and heating
consisting of a multilayer structure of polyvinylidene fluoride nanofiber/zinc
oxide nanosheet/carbon nanotube/Ag nanowire/polydimethylsiloxane was
fabricated for comprehensive thermal management applications. In the
cooling mode, the high thermal radiation emissivity (89.2%) and sunlight
reflectivity (90.6%) of the Janus membrane resulted in huge temperature
drops of 8.2–12.6, 9.0–14.0, and 10.9 °C for a
substrate, a closed space, and a semiclosed space, respectively. When
switching to the heating mode, temperature rises of 3.8–4.6,
4.0–4.8, and 12.5 °C for the substrate, closed space,
and semiclosed space, respectively, were achieved owing to the high
thermal radiation reflectivity (89.5%) and sunlight absorptivity (74.1%)
of the membrane. Besides, the Janus membrane has outstanding comprehensive
properties of the membrane, including infrared camouflaging/disguising,
electromagnetic shielding (53.1 dB), solvent tolerance, waterproof
properties, and high flexibility, which endow the membrane with promising
application prospects.