Preparation and application of stimuli-responsive PET TeMs: RAFT graft block copolymerisation of styrene and acrylic acid for the separation of water–oil emulsions

Muslimova, Indira B.; Zhumanazar, Nurdaulet; Melnikova, Galina B.; Yeszhanov, Arman B.; Zhatkanbayeva, Zhanna K.; Chizhik, Sergei A.; Zdorovets, Maxim V.; Güven, Olgun; Korolkov, Ilya V.

doi:10.1039/d4ra02117g

Cited by 3 publications

(2 citation statements)

References 55 publications

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“…Track-etched membranes (TeMs) are a highly versatile and extensively researched material used for water filtration, cell cultivation, catalysts, sensors and others [19][20][21]. TeMs are manufactured by irradiation of thin polymer films with heavy ions to create distinct tracks and subsequent chemical etching.…”

Section: Introductionmentioning

confidence: 99%

Surface Modification of Polyethylene Terephthalate Track-Etched Membranes by 2,2,3,3,4,4,5,5,6,6,7,7- Dodecafluoroheptyl Acrylate for Application in Water Desalination by Direct Contact Membrane Distillation

Shakayeva,

Yeszhanov,

Borissenko

et al. 2024

Preprint

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In this work, the surface of poly(ethylene terephthalate) track-etched membranes (PET TeMs) with pore sizes of 670-1310 nm was hydrophobized with 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl acrylate (DFHA) by photoinitiated graft polymerization. Attenuated total reflection FTIR spec-troscopy (ATR-FTIR), scanning electron microscopy (SEM) coupled to an energy-dispersive X-ray spectrometer (EDX), and contact angle measurement were used to identify and characterize the TeMs. The optimal parameters for graft polymerization were determined as follows: polymeriza-tion time 60 min, monomer concentration of 30% and distance from the UV-source 7 cm. The wa-ter contact angle of the modified membranes reached 97° which is 51o for pristine membranes. The modified membranes were tested for water desalination using direct contact membrane distillation (DCMD) method. The effect of membrane pore size, the degree of grafting and salt concentration on the performance of membrane distillation process was investigated. According to the results obtained, it has been concluded that large pore size hydrophobic TeMs modified by using DFHA could be used for desalinating water.

show abstract

Section: Introductionmentioning

confidence: 99%

Surface Modification of Polyethylene Terephthalate Track-Etched Membranes by 2,2,3,3,4,4,5,5,6,6,7,7- Dodecafluoroheptyl Acrylate for Application in Water Desalination by Direct Contact Membrane Distillation

Shakayeva,

Yeszhanov,

Borissenko

et al. 2024

Preprint

View full text Add to dashboard Cite

show abstract

“…Track-etched membranes (TeMs) are a highly versatile and extensively researched material used for water filtration, cell cultivation, catalysts, sensors, and other applications [19][20][21]. TeMs are manufactured by irradiation of thin polymer films with heavy ions to create distinct tracks and subsequent chemical etching.…”

Section: Introductionmentioning

confidence: 99%

Surface Modification of Polyethylene Terephthalate Track-Etched Membranes by 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl Acrylate for Application in Water Desalination by Direct Contact Membrane Distillation

Shakayeva,

Yeszhanov,

Borissenko

et al. 2024

Membranes

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In this work, the surfaces of poly (ethylene terephthalate) track-etched membranes (PET TeMs) with pore sizes of 670–1310 nm were hydrophobized with 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl acrylate (DFHA) by photoinitiated graft polymerization. Attenuated total reflection FTIR spectroscopy (ATR-FTIR), scanning electron microscopy (SEM) coupled to an energy-dispersive X-ray spectrometer (EDX), and contact angle measurements were used to identify and characterize the TeMs. The optimal parameters for graft polymerization were determined as follows: polymerization time of 60 min, monomer concentration of 30%, and distance from the UV source of 7 cm. The water contact angle of the modified membranes reached 97°, which is 51° for pristine membranes. The modified membranes were tested for water desalination using direct contact membrane distillation (DCMD) method. The effects of membrane pore size, the degree of grafting, and salt concentration on the performance of membrane distillation process were investigated. According to the results obtained, it has been concluded that large pore size hydrophobic TeMs modified by using DFHA could be used for desalinating water.

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Composite Track-Etched Membranes: Synthesis and Multifaced Applications

Mashentseva,

Sutekin,

Rakisheva

et al. 2024

Polymers

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Composite track-etched membranes (CTeMs) emerged as a versatile and high-performance class of materials, combining the precise pore structures of traditional track-etched membranes (TeMs) with the enhanced functionalities of integrated nanomaterials. This review provides a comprehensive overview of the synthesis, functionalization, and applications of CTeMs. By incorporating functional phases such as metal nanoparticles and conductive nanostructures, CTeMs exhibit improved performance in various domains. In environmental remediation, CTeMs effectively capture and decompose pollutants, offering both separation and detoxification. In sensor technology, they have the potential to provide high sensitivity and selectivity, essential for accurate detection in medical and environmental applications. For energy storage, CTeMs may be promising in enhancing ion transport, flexibility, and mechanical stability, addressing key issues in battery and supercapacitor performance. Biomedical applications may benefit from the versality of CTeMs, potentially supporting advanced drug delivery systems and tissue engineering scaffolds. Despite their numerous advantages, challenges remain in the fabrication and scalability of CTeMs, requiring sophisticated techniques and meticulous optimization. Future research directions include the development of cost-effective production methods and the exploration of new materials to further enhance the capabilities of CTeMs. This review underscores the transformative potential of CTeMs across various applications and highlights the need for continued innovation to fully realize their benefits.

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Preparation and application of stimuli-responsive PET TeMs: RAFT graft block copolymerisation of styrene and acrylic acid for the separation of water–oil emulsions

Abstract: In this study, we present a method to fabricate pH-sensitive membranes using UV-initiated RAFT graft copolymerization of styrene and acrylic acid on PET track-etched membranes for separation of water–oil emulsions.

Cited by 3 publications

References 55 publications

Surface Modification of Polyethylene Terephthalate Track-Etched Membranes by 2,2,3,3,4,4,5,5,6,6,7,7- Dodecafluoroheptyl Acrylate for Application in Water Desalination by Direct Contact Membrane Distillation

Surface Modification of Polyethylene Terephthalate Track-Etched Membranes by 2,2,3,3,4,4,5,5,6,6,7,7- Dodecafluoroheptyl Acrylate for Application in Water Desalination by Direct Contact Membrane Distillation

Surface Modification of Polyethylene Terephthalate Track-Etched Membranes by 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl Acrylate for Application in Water Desalination by Direct Contact Membrane Distillation

Composite Track-Etched Membranes: Synthesis and Multifaced Applications

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