1999
DOI: 10.1039/a901263j
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Preparation and characterisation of a highly active bimetallic (Pd–Ru) nanoparticle heterogeneous catalyst†

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Cited by 136 publications
(102 citation statements)
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“…In fact, studies involving cluster-based nanoparticle catalysts even highlighted the integral importance of site-15 isolation as well as particle size in enhancing efficiency of catalytic oxidations and hydrogenations. [20][21][22][23][24][25] The nature of support materials has ranged from metal oxides 26 and carbonaceous materials, 27 to microporous alternatives such as zeolites 28,29 or metal-organic frameworks 20 (MOFs), 30,31 and mesoporous silica-derived hosts 32 such as MCM-41 or SBA-15. Nanoporous materials have been extensively explored for their intrinsic catalytic properties, 33 however isolated single-sites in the form of doped frameworks [34][35][36] or supported nanoparticles have proved to be 25 superior.…”
Section: Figurementioning
confidence: 99%
“…In fact, studies involving cluster-based nanoparticle catalysts even highlighted the integral importance of site-15 isolation as well as particle size in enhancing efficiency of catalytic oxidations and hydrogenations. [20][21][22][23][24][25] The nature of support materials has ranged from metal oxides 26 and carbonaceous materials, 27 to microporous alternatives such as zeolites 28,29 or metal-organic frameworks 20 (MOFs), 30,31 and mesoporous silica-derived hosts 32 such as MCM-41 or SBA-15. Nanoporous materials have been extensively explored for their intrinsic catalytic properties, 33 however isolated single-sites in the form of doped frameworks [34][35][36] or supported nanoparticles have proved to be 25 superior.…”
Section: Figurementioning
confidence: 99%
“…For example, organometallic cluster precursors containing two different metals have been used to prepare supported bimetallic catalysts, but continuous variation of the elemental composition of the resulting particles requires large precursor libraries. [14][15][16] Most other methods for preparing supported bimetallic nanoparticles in the <5-nm size range lead to phase segregation of the two metals and thus poor control over the composition of individual particles, 17 although limited success has been achieved using surfactant-stabilized nanoparticles. 18 We prepared DENs consisting of PdAu alloys within fourthgeneration, amine-terminated poly(amidoamine) (PAMAM) dendrimers (G4-NH 2 (Pd n Au 55-n )) by co-complexation of the two corresponding metal salts followed by chemical reduction of the dendrimer/metal-ion composite.…”
mentioning
confidence: 99%
“…Along with our colleagues, Johnson et al [47][48][49][50] we have shown that monodisperse mixed-metal cluster carbonylates may be uniformly incorporated inside mesoporous silica and gently decarbonylated to yield the naked clusters, which are anchored securely to the underlying silica ( Figure 12). The key point in this case is to recognize that the method of preparation produces 1) clusters that are of the same stoi- 2À is readily sequestered within the mesopores of silica in the presence of the molecular cation PPN + (bis(triphenylphosphine)iminium).…”
Section: Individual Isolated Bimetallic Clusters As Single-site Hetmentioning
confidence: 88%
“…Turnover frequencies associated with {Pd 6 Ru 6 } nanoclusters in the hydrogenation of a typical alkene exceed by an order of magnitude those for monoelemental palladium or ruthenium clusters. [48] The structures of these nanoparticle bimetallic clusters are determined (usually under in situ catalytic conditions) by X-ray absorption spectroscopy. Two examples are shown in Figure 14.…”
Section: Individual Isolated Bimetallic Clusters As Single-site Hetmentioning
confidence: 99%