Preparation and characterization of 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin grafted on organosilane-pillared montmorillonite by covalent bonding

Enhancement of photoelectrocatalytic performance of copper cobaltate nanoflowers modified with 5,10,15,20-tetrakis(4-carboxylphenyl)porphyrin for methanol oxidation under light

“…A similar phenomenon has been demonstrated in the field of photocatalysis. 20,21 For example, Apaydin et al 22 integrated CuTPP-COOH with TiO 2 NTs to obtain a new low-cost photocathode that can reduce dissolved O 2 to H 2 O 2 with high efficiency.…”

“…A similar phenomenon has been demonstrated in the field of photocatalysis. 20,21 For example, Apaydin et al 22 O, 30 mmol ammonium fluoride, and 50 mmol urea were added to deionized water (70 mL), followed by magnetic stirring (1 h). The solution after magnetic stirring was transferred to a Teflonlined autoclave (100 mL) and hydrothermally heated at 120 °C for 6 h. After cooling, the sample was washed by centrifugation with water and ethanol, and then dried at 60 °C.…”

Enhanced Performance of Porphyrin-Modified CuO-Co3O4 Heterojunction as a Photoelectrocatalyst for Methanol Oxidation

“…Compared with Cu 2 Co 1 , TCPP/Cu 2 Co 1 shows N 1s peaks at binding energies of 398.6 and 400.4 eV, and these two peaks correspond to the −N-bond and −N� bond on the porphyrin ring. 24,42 Additionally, both TCPP and TCPP/Cu 2 Co 1 have four porphyrin absorption peaks in the 1000−2000 cm −1 range from the Fourier-transform infrared (FT-IR) test plot (Figure 2F). 43,44 The above results indicate that the porphyrin was successfully modified onto the surface of Cu 2 Co 1 .…”

Synthesis and Characterization of New Nanocomposites Based on Montmorillonite and Hexahydroquinolinyl Ether Hybrids

“…So, these molecules are easily desorbed from the surface, resulting in decreasing the efficiency of the composites. Therefore,it is important to combine organic functional molecules with MMT by chemical bonds especially co‐ordinate bonds, which reinforce the stability of the composites and extends the pH range in practical application [10,11] …”