a b s t r a c tWe report the fabrication and characterization of a Ti 4 þ : Tm 3 þ : LiNbO 3 optical waveguide in view of photon-echo quantum memory applications. Specifically, we investigated room-and cryogenictemperature properties of the waveguide, and the Tm 3 þ ions, via absorption, spectral hole burning, photon echo, and Stark spectroscopy. For the Tm 3 þ ions, we found radiative lifetimes of 82 ms and 2.4 ms for the 3 H 4 and 3 F 4 levels, respectively, and a 44% branching ratio from the 3 H 4 to the 3 F 4 level.We also measured an optical coherence time of 1:6 ms for the 3 H 6 2 3 H 4 , 795 nm wavelength transition, and investigated the limitation of spectral diffusion to spectral hole burning. Upon application of magnetic fields of a few hundred Gauss, we observed persistent spectral holes with lifetimes up to seconds. Furthermore, we measured a linear Stark shift of 25 kHz cm=V. Our results are promising for integrated, electro-optical, waveguide quantum memory for photons.