contaminated water becomes an environmental hazard.Functional photocatalytic nanofiber webs [6,7] are promising environmentally friendly candidates for the photodegradation of organic pollutants, such as dyes and pigments. Nanofibers have high specific morphology, [8] small diameter [9] and small pore size, [10] and customizable physicochemical characteristics, [11] which make them excellent candidates in wastewater treatment, [12] biomedical applications, [13][14][15] protein purification, [16] and air filtration. [17] Poly(vinylidene fluoride) (PVDF) [18] is a commonly used hydrophobic polymer for wastewater treatment, due to its excellent thermal stability, mechanical stability, chemical resistance, and selective permeability. However, interception effect (meaning large particles would be intercepted by small pore size nanofiber webs), the major ultrafiltration mechanism for unfunctionalized PVDF nanofiber webs, [19] limits their applications because of their low filtration efficiency and poor functionality. The addition of nanoparticles could improve the photocatalytic properties, [20] mechanical properties, [21] hydrophobicity, [22,23] and other functional performances of nanofiber webs. [19][20][21][22][23] Moreover, physical modification methods (addition of functional nanoparticles) have proved to be simpler and more effective than chemical modification methods. [24] Commonly used nanoparticles include titanium dioxide (anatase TiO 2 ), [25] zinc oxide (ZnO), [26] aluminum oxide (Al 2 O 3 ), [27] magnetite (Fe 3 O 4 ), [28] graphite oxide (GO), [29] multiwalled carbon nanotubes (MWCNTs), [30] and polymeric nanoparticles. [31] Polymeric nanoparticles, including nanospheres and nanocapsules, are formed by a polymeric matrix and mainly used for drug delivery, where the molecules are absorbed in or on the matrix, for example, encapsulation of insulin in poly(lactic-co-glycolic acid) nanoparticles. [32] Among these nanoparticles, anatase titanium dioxide is the most widely used catalyst for water treatment because of low cost, stability in water, and high photocatalytic property. [19][20][21] The addition of TiO 2 in nanofiber webs can greatly improve the degradation rate of organic pigments/dyes pollutants, [19] antibacterial properties, [20] and other performances (antifouling property, wettability). [20,21,23] Electrospinning is a popular and simple method to produce functional nanofiber webs among all existing nanofiber webs technologies, such as melt spinning, solution spinning, andThe photodegradation of poly(vinylidene fluoride) (PVDF)/titanium oxide (TiO 2 ) nanofibers under visible light is described, something that has not been previously reported in the literature. Visible light photocatalytic electrospun PVDF/TiO 2 nanofiber webs with anatase TiO 2 concentration varying from 0% to 20% (0%, 1%, 3%, 5%, 10%, and 20%) are produced, and their ability to degrade a toxic pollutant, Rhodamine B (RhB), is studied. Photodegradation study using UV-vis spectroscopy on PVDF/TiO 2 nanofiber webs (with TiO 2 con...