Main observation and conclusion
Developing multi‐element composites is a promising way for high performance supercapacitor material development, and simplifying the synthesis steps is critical for reducing the preparation costs and successful promotion of the materials. A novel one‐step selective reaction strategy is developed, and successfully used to prepare four‐element ZnO‐CoSe2 (ZOCS) nano‐spherical composites, to be used as supercapacitor materials. Started form nano‐spherical glycerate templates, under the optimal synthesis condition, the obtained ZOCS‐0.125 electrode material exhibits a specific capacitance of 450.7 F/g at 1 A/g and a good rate performance by keeping 76.8% capacitance at 20 A/g. Moreover, the ZOCS‐0.125 electrode exhibits excellent cycle stability of 114.9% capacitance retention after 5000 cycles at 10 A/g. An asymmetric supercapacitor assembled by ZOCS‐0.125 and activated carbon electrodes delivers an energy density of 22.35 Wh/kg at 825 W/kg, and a cycle stability of 105.6% capacitance retention after 5000 cycles. This work not only shows the good potential of the facilely prepared ZnO‐CoSe2 composite electrode material, but also demonstrates a new strategy for low cost and high performance multielement composite material development, that can be used in a wide range of applications.