Use of silicon dioxide (SiO 2 ) and titanium dioxide (TiO 2 ) have been widely investigated individually in coatings technology, but their combined properties promote compatibility for different innovative applications. For example, the photocatalytic properties of TiO 2 coatings, when exposed to UV light, have interesting environmental applications, such as air purification, self-cleaning and antibacterial properties. However, as reported in different pilot projects, serious durability problems, associated with the adhesion between the substrate and TiO 2 , have been evidenced. Thus, the aim of this work is to synthesize SiO 2 together with TiO 2 to increase the durability of the photocatalytic coating without affecting its photocatalytic potential. Therefore, synthesis using sonochemistry, synthesis without sonochemistry, physical characterization, photocatalytic evaluation, and durability of the SiO 2 , SiO 2 @TiO 2 and TiO 2 coatings are presented. Results indicate that using SiO 2 improved the durability of the TiO 2 coating without affecting its photocatalytic properties. Thus, this novel SiO 2 @TiO 2 coating shows potential for developing long-lasting, self-cleaning and air-purifying construction materials.