Structure and physico-chemical properties of a photocatalyst, especially surface area and absorption ability, were correlated to catalytic activities in photodegradation of dye pollutants in water. In this investigation photocatalytic degradation of azo dye Direct yellow 12 (Chrysophenine G) in water was studied. Titanium(IV) oxide was supported on Clinoptilolite (CP) (Iranian Natural Zeolite) using solid-state dispersion (SSD) method. The results show that the TiO 2 /Clinoptilolite (SSD) is an active photocatalyst. The maximum effect of photo degradation was observed at 10 wt.% TiO 2 , 90 wt.% Clinoptilolite. A first order reaction with k = 0.0108 min -1 was observed. The effects of some parameters such as pH, amount of photocatalyst, initial concentration of dye were examined.