Preparation and crystal and molecular structure of tris(pentamethylenedithiocarbamato) indium(III), In(pmtc)3

Hauser, P. J.; Bordner, Jon; Schreiner, A. F.

doi:10.1021/ic50124a026

Cited by 28 publications

(10 citation statements)

References 3 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…1087 (12) 1172 (12) 5362 (7) 9 Auf Grund von Strukturvergleichen ähnlicher Verbindungen mit Dithioliganden [5][6][7][8][15][16][17][18] war zu vermuten, daß auch im vorliegenden Fall Dithiocarbamat und Xanthogenat zweifach an die Zentralatome koordinieren. Zusätz-liche Hinweise dafür waren einerseits dem 1.H-NMR-Spektrum der Bismutverbindung entnommen worden [12], andererseits lag auch im Falle der Thalliumverbindung mit deren besonderer Stabilität [13] ein entsprechendes Indiz vor.…”

Section: Introductionunclassified

“…Zusätzliche intermolekulare Wechselwirkungen lassen sich im Gegensatz zu den bei CHaBi(S2CN(C2H5)2)2 [15] gefundenen Verhältnissen nicht feststellen, und es bestehen auch keine Anzeichen dafür, daß andere potentielle Koordinationsstellen der Liganden (außer Schwefel) an der Koordination beteiligt werden, wie es z. B. von (CHa)2TIS2COCHa [8] mitgeteilt wurde.…”

Section: Introductionunclassified

See 1 more Smart Citation

Die Kristallstruktur von p‐Tolylbis(diethyldithiocarbamato)‐thallium(III) und Phenylbis(methylxanthogenato)bismut(III)

Burschka

1982

Zeitschrift anorg allge chemie

View full text Add to dashboard Cite

show abstract

Section: Introductionunclassified

Die Kristallstruktur von p‐Tolylbis(diethyldithiocarbamato)‐thallium(III) und Phenylbis(methylxanthogenato)bismut(III)

Burschka

1982

Zeitschrift anorg allge chemie

View full text Add to dashboard Cite

show abstract

“…The three bidentate dialkyldithiocarbamate ligands impose a hexacoordinated arrangement around the indium atom. The structures of tris(diethyldithiocarbamate) of indium(III) [3] and the related pyperidine analog, In[S 2 CN(C 2 H 5 ) 2 ] 3 , have been determined [16] and easily corroborate with this proposition. Thus, in both the cases it was found that the InS 6 kernel is a highly distorted octahedral with symmetry near D 3 .…”

Section: Inx Rs à Sr 3 Xinsrmentioning

confidence: 57%

“…The existence of two signals for the methyne protons and carbon seems to suggest two different coordination modes of the ligand in solution; as known for dialkyldithiocarbamates [16] that can bond to the central metal atom in a conventional bidentate con®guration involving two ' bonding orbitals of the metal or as a three-centered bonded ligand as follows:…”

Section: Inx Rs à Sr 3 Xinsrmentioning

confidence: 99%

N,N′-Dialkyldithiocarbamate chelates of indium(III): alternative synthetic routes and thermodynamics characterization

Oliveira¹,

Pessoa²,

Carvalho³

et al. 1999

Thermochimica Acta

View full text Add to dashboard Cite

Alternative synthetic routes to prepare N,N H -dialkyldithiocarbamate complexes of indium(III), In(S 2 CNR 2 ) 3 (R CH 3 , C 2 H 5 , n-C 3 H 7 , i-C 3 H 7 , n-C 4 H 9 and i-C 4 H 9 ) from the metallic element and from indium monohalides, InX(X Cl, Br and I) were established. The proposed mechanism of reaction involving InX considering a ligand redistribution reaction of XIn(S 2 C± NR 2 ) 2 initially produced, which could be derived from the insertion of InX into sulfur±sulfur bond of the tetralkylthiuram disul®de. The thermal decomposition of the In(S 2 CNR 2 ) 3 (R CH 3 , C 2 H 5 , n-C 3 H 7 , i-C 3 H 7 , n-C 4 H 9 and i-C 4 H 9 ) compounds was investigated by the thermogravimetric technique, where two pathways were detected, depending on the dialkyldithiocarbamato ligand. The ®rst step leads to indium metal, or alternatively In 2 S 3 , as the ®nal residue for R C 2 H 5 , n-C 3 H 7 , i-C 4 H 9 and for R CH 3 , i-C 3 H 7 , n-C 4 H 9 , respectively. The corresponding standard molar enthalpies of sublimation of all compounds were determined by means of differential scanning calorimetry and methods of estimation. #

show abstract

“…12,18,[21][22][23]25,30,31,33,38,39,47,49,[52][53][54][55][56][57][58][59][60][61][62][63][64][65][66][67] The complexes are discrete monomers and in general have distorted geometries owing to the restricted bite of the dithio ligands. The S-M-S angle of the chelating dithio ligands varies between 66⋅6 and 81⋅7°, the Scheme 1.…”

Section: Structuresmentioning

confidence: 99%

Gallium(III) and indium(III) dithiolate complexes: Versatile precursors for metal sulfides

Ghoshal

Jain

2007

J Chem Sci

View full text Add to dashboard Cite

The chemistry of classical and organometallic complexes of gallium and indium with dithiolate ligands, i.e., dithiocarboxylates, xanthates, dithiocarbamates, dithiophosphates, dithiophophinates and dithioarsenates, has been reviewed. Synthesis, spectroscopic and structural aspects of these complexes are described. Their emerging role as single source molecular precursors for the preparation of metal sulfide thin films and nano-particles has been discussed.

show abstract

Preparation and crystal and molecular structure of tris(pentamethylenedithiocarbamato) indium(III), In(pmtc)3

Cited by 28 publications

References 3 publications

Die Kristallstruktur von p‐Tolylbis(diethyldithiocarbamato)‐thallium(III) und Phenylbis(methylxanthogenato)bismut(III)

Die Kristallstruktur von p‐Tolylbis(diethyldithiocarbamato)‐thallium(III) und Phenylbis(methylxanthogenato)bismut(III)

N,N′-Dialkyldithiocarbamate chelates of indium(III): alternative synthetic routes and thermodynamics characterization

Gallium(III) and indium(III) dithiolate complexes: Versatile precursors for metal sulfides

Contact Info

Product

Resources

About