Preparation and Crystal Structures of Silver(I), Mercury(II), and Lead(II) Complexes of Oxathia-Tribenzo-Macrocycles

Siewe, Arlette Deukam; Ju, Huiyeong; Lee, Shim Sung

doi:10.5012/bkcs.2013.34.3.725

Cited by 4 publications

(1 citation statement)

References 28 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In the last few years, much effort has been focused on the generation of inorganic arrays of various types in view of their promising physico-chemical properties and their potential application in nano-technology. [1][2][3][4][5] Among the various arrays, there is an increasing interest in [2×2] grid-shaped complexes based on ligands containing pyrimidine-type or pyridine-type groups and various transition metal ions. These grids are thermodynamically most stable when metal ions of tetrahedral or octahedral coordination geometry are combined with a planar ligand containing polydentate binding subunits.…”

Section: Introductionmentioning

confidence: 99%

Hydrothermal Synthesis, Crystal Structures and Properties of Zinc(II) Di-nuclear Complex and Copper(I) Coordination Polymer Based on Building Block 2-Phenyl-4,6-di(pyridin-2-yl)pyrimidine

Zhao¹,

Wang²,

Jiang³

et al. 2013

Bulletin of the Korean Chemical Society

View full text Add to dashboard Cite

A tetradentate ligand of 2-phenyl-4,6-di(pyridin-2-yl)pyrimidine (L) has been synthesized and its complexes with ZnI 2 and CuI have been obtained by hydrothermal method. single crystal X-ray diffraction analysis indicates that ligand L coordinates with Zn(II) ions to form a simple four-coordinate di-nuclear complex, while the complexation of L with Cu(I) constructs a one-dimensional chain polymer. The existence of I -ion hampers the L to assemble grid-type complexes with Zn(II) and Cu(I). Fluorescence spectra show that the L emits blue fluorescence while its Cu(I) polymer decrease the fluorescence intensity and Zn(II) complex quenches the fluorescence.

show abstract

Section: Introductionmentioning

confidence: 99%

Hydrothermal Synthesis, Crystal Structures and Properties of Zinc(II) Di-nuclear Complex and Copper(I) Coordination Polymer Based on Building Block 2-Phenyl-4,6-di(pyridin-2-yl)pyrimidine

Zhao¹,

Wang²,

Jiang³

et al. 2013

Bulletin of the Korean Chemical Society

View full text Add to dashboard Cite

show abstract

Syntheses and Crystal Structures of a Novel 20‐Membered N₃O₂‐Donor Macrocycle and Its Disilver(I) Bis(Macrocycle) and Monocadmium(II) Complexes

Kang

Choi

2015

Bulletin Korean Chem Soc

View full text Add to dashboard Cite

In macrocyclic coordination chemistry, the cation to cavity size ratio is an important parameter for understanding complexation-based metal ion recognition.1 For example, 16-to 19-membered ring ligands incorporating dibenzo subunits have been widely investigated because these ligands generally favor stable 1:1 complexation and show intermediate flexibility which limits the number of observed complex conformations. 1,2Following these earlier studies, new synthetic results and applications for the related macrocyclic systems have continued up to the present. 3 In terms of macrocyclic cavity sizes, macrocyclic rings greater than 24-membered are strong candidates for forming dinuclear complexes in both the synthetic and bioinorganic chemistry areas. 4 However, their preparation and purification tend to be difficult, often leading to the formation of the target ring in low yield.On the other hand, the preparation and structural characterization of the complexes with 20-to 23-membered macrocycles have been less investigated because their cavity sizes are too large for planar complexation with one metal ion but too small for coordination with two metal ions simultaneously. 5 However, macrocycles with the 20-23 membered rings are expected to give the unusual coordination topologies, while another advantage is that the latter category is usually relatively easier to prepare than larger analogs. Recently, several kinds of 20-to 23-membered oxathia-tribenzo macrocycles and their discrete and polymeric complexes showing less common stoichiometric ratios have been reported. 5 To the best of our knowledge, such 20-membered O 2 N 3 -donor analogs have not been reported so far.In this work, we present a 20-membered O 2 N 3 -macrocycle L incorporating a tribenzo-subunit (Scheme 1); L is a potentially pentadentate macrocyclic ligand which is expected to react with a wide range of metal species. In particular, d 10 metal ions are free from formation of specific coordination geometries and often show favorable reactivity toward polyoxaaza ligand systems. Here we report the synthesis of L along with an X-ray study of its complexes incorporating the d 10 -metal ions Cd(II) and Ag(I). The novel tribenzo-O 2 N 3 -macrocycle L was obtained directly in 75% yield from reaction of dialdehyde 6 with diethylenetriamine in methanol followed by sodium borohydride reduction. The 1 H and 13 C NMR spectra together with elemental analysis and mass spectra were all in agreement with the proposed structure.Reaction of L with Cd(NO 3 ) 2 Á4H 2 O in dichloromethane/ methanol afforded a colorless crystalline product 1 suitable for X-ray analysis (Table 1). The crystal structure of 1 is shown in Figure 1 and its selected geometric parameters are presented in Table 2. The crystal structure of 1 has an anion-coordinated mononuclear arrangement with the formula being [Cd(L) (NO 3 ) 2 ]. Unlike our expectation, the Cd(II) center locates outside the macrocyclic cavity (Figure 1(a)). The Cd(II) center is in a hexa-coordinated environment, being bound to th...

show abstract

Ten-Membered Rings or Larger With One or More Oxygen and Sulfur Atoms

Ju¹,

Lee²,

Ikeda³

et al. 2022

Comprehensive Heterocyclic Chemistry IV

View full text Add to dashboard Cite

Preparation and Crystal Structures of Silver(I), Mercury(II), and Lead(II) Complexes of Oxathia-Tribenzo-Macrocycles

Cited by 4 publications

References 28 publications

Hydrothermal Synthesis, Crystal Structures and Properties of Zinc(II) Di-nuclear Complex and Copper(I) Coordination Polymer Based on Building Block 2-Phenyl-4,6-di(pyridin-2-yl)pyrimidine

Hydrothermal Synthesis, Crystal Structures and Properties of Zinc(II) Di-nuclear Complex and Copper(I) Coordination Polymer Based on Building Block 2-Phenyl-4,6-di(pyridin-2-yl)pyrimidine

Syntheses and Crystal Structures of a Novel 20‐Membered N₃O₂‐Donor Macrocycle and Its Disilver(I) Bis(Macrocycle) and Monocadmium(II) Complexes

Ten-Membered Rings or Larger With One or More Oxygen and Sulfur Atoms

Contact Info

Product

Resources

About

Preparation and Crystal Structures of Silver(I), Mercury(II), and Lead(II) Complexes of Oxathia-Tribenzo-Macrocycles

Cited by 4 publications

References 28 publications

Hydrothermal Synthesis, Crystal Structures and Properties of Zinc(II) Di-nuclear Complex and Copper(I) Coordination Polymer Based on Building Block 2-Phenyl-4,6-di(pyridin-2-yl)pyrimidine

Hydrothermal Synthesis, Crystal Structures and Properties of Zinc(II) Di-nuclear Complex and Copper(I) Coordination Polymer Based on Building Block 2-Phenyl-4,6-di(pyridin-2-yl)pyrimidine

Syntheses and Crystal Structures of a Novel 20‐Membered N3O2‐Donor Macrocycle and Its Disilver(I) Bis(Macrocycle) and Monocadmium(II) Complexes

Ten-Membered Rings or Larger With One or More Oxygen and Sulfur Atoms

Contact Info

Product

Resources

About

Syntheses and Crystal Structures of a Novel 20‐Membered N₃O₂‐Donor Macrocycle and Its Disilver(I) Bis(Macrocycle) and Monocadmium(II) Complexes