Preparation and electrochemical properties of surface-charge-modified Zn2SnO4 nanoparticles as anodes for lithium-ion batteries

Kim, Kyung-Ho; Annamalai, A.; Park, Su Han; Kwon, Tae Hyung; Pyeon, Mu Wook; Lee, Man−Jong

doi:10.1016/j.electacta.2012.04.121

Cited by 49 publications

(29 citation statements)

References 49 publications

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“…The hydrothermal method is one of the most common preparation routes for zinc stannate . The inverse spinel structure of Zn 2 SnO 4 was prepared with different amounts of alkaline mineralizer (NaOH) .…”

Section: Stannate Anodesmentioning

confidence: 99%

Recent Developments and Understanding of Novel Mixed Transition‐Metal Oxides as Anodes in Lithium Ion Batteries

Zhao

Yan

et al. 2016

Advanced Energy Materials

821

374

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improved LIB performance is in the electrode materials. [ 11 ] Presently, commercial anode materials mainly include graphite, which limits the lithium storage performance in terms of energy and power density due to the low theoretical capacity (LiC 6 , 372 mAh g −1 ) and low Li-ion transport rate. [12][13][14] New anode materials with higher capacities are being looked for including mixed transition metal oxide anodes. Traditional Metal Oxide AnodesNew research is constantly being carried out to reach the high requirements for LIB anodes. Various metal oxide materials such as SnO 2 , [15][16][17][18][19] Co 3 O 4 , [20][21][22][23] NiO, [24][25][26][27] Fe 3 O 4 , [28][29][30] and MnO 2 [31][32][33] are alternative potential anodes for LIBs due to their high theoretical capacities, high power density, and wide usefulness. However, metal oxides inevitably suffer from several major problems: severe volume changes during the alloying-dealloying processes, pulverization and agglomeration of primitive particles, and poor electronic conductivity that hinders the reaction with lithium during electrochemical reactions. Numerous approaches have attempted to address these challenges. One useful method is to develop the metal oxide materials into nanostructures. [ 3 ] The distinct lithium storage mechanisms and the infl uence of unique structures on the lithium storage properties of the metal oxide materials have been reported in detail. [ 5 ] A series of work on the design of various nanostructures of metal oxide materials has been subsequently carried out, for nanomaterials of different dimensions, hollow structures, and hierarchical structures. [ 5 ] Coating or combining the buffering matrix or conductive materials with metal oxide materials is another way to relieve the severe problems. [36][37][38][39][40][41][42] Various carbon materials, especially novel nanocarbon materials like carbon nanotubes and graphene nanosheets, have been widely studied as the buffering and conductive agent for metal oxide anodes. [43][44][45][46] In our previous review, [ 47 ] the signifi cant effects of graphene nanosheets on tin-based anodes were summarized in detail. It has been concluded that graphene not only contributes as a highly conductive network, but also as a fl exible supporting layer, effectively relieving the volume change and particle aggregation. In addition, different metals and metal oxides that are electrochemically active and Mixed transition-metal oxides (MTMOs), including stannates, ferrites, cobaltates, and nickelates, have attracted increased attention in the application of high performance lithium-ion batteries. Compared with traditional metal oxides, MTMOs exhibit enormous potential as electrode materials in lithium-ion batteries originating from higher reversible capacity, better structural stability, and high electronic conductivity. Recent advancements in the rational design of novel MTMO micro/nanostructures for lithium-ion battery anodes are summarized and their energy storage mechanism is compared to transit...

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Section: Stannate Anodesmentioning

confidence: 99%

Recent Developments and Understanding of Novel Mixed Transition‐Metal Oxides as Anodes in Lithium Ion Batteries

Zhao

Yan

et al. 2016

Advanced Energy Materials

821

374

View full text Add to dashboard Cite

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“…Control of the morphology and mean size of the metal sulfide and metal sulfide-carbon composite materials is, however, essential to their efficient application in LIBs. Spherical micron-sized powders have been successfully applied as anode materials for LIBs owing to their high packing density on the current collector [33,34]. However, the efficient large-scale production of spherical micron-sized metal sulfide-carbon composite materials with suitable structures for application in LIBs has been scarcely studied.…”

Section: Introductionmentioning

confidence: 99%

Electrochemical properties of MnS–C and MnO–C composite powders prepared via spray drying process

Jeon

Cho

2015

Journal of Power Sources

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“…Kim et al . [ 64 ] compared Zn 2 SnO 4 nanoparticles synthesized with Na 2 CO 3 and tert ‐butyl amine. Inorganic Na 2 CO 3 with negative surface charges could induce the formation of planar morphologies.…”

Section: Applications Of Zn2sno4 Nanostructuresmentioning

confidence: 99%

“…(a) Cycling performance and coulombic efficiencies of Zn 2 SnO 4 synthesized with Na 2 CO 3 and tert ‐butyl amine; [ 64 ] (b) schematic diagram for the formation mechanism of the Zn 2 SnO 4 –carbon composite microsphere. [ 67 ] …”

Section: Applications Of Zn2sno4 Nanostructuresmentioning

confidence: 99%

Zinc Stannate Nanostructures for Energy Conversion^†

Dou

Chen

2021

Chin. J. Chem.

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To date, ternary metal oxide semiconductor materials have attracted extensive attention worldwide due to their unique optoelectronic properties. As a classical ternary oxide, Zn2SnO4 is featured with the high electron mobility, wide band gap, negligible visible light absorption and tailorable electronic band structures. Thus, it is an ideal material for practical use in solar cells, lithium batteries, sensors, and photo‐catalysts. In this review, we summarize the recent research progress of this material with the focus on the synthesis methods, nanostructures, and the resulting effects on the crystal structure, optical properties, and photoelectrochemical properties. Moreover, their potential applications in different devices are highlighted and carefully discussed.

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Preparation and electrochemical properties of surface-charge-modified Zn2SnO4 nanoparticles as anodes for lithium-ion batteries

Cited by 49 publications

References 49 publications

Recent Developments and Understanding of Novel Mixed Transition‐Metal Oxides as Anodes in Lithium Ion Batteries

Recent Developments and Understanding of Novel Mixed Transition‐Metal Oxides as Anodes in Lithium Ion Batteries

Electrochemical properties of MnS–C and MnO–C composite powders prepared via spray drying process

Zinc Stannate Nanostructures for Energy Conversion^†

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Preparation and electrochemical properties of surface-charge-modified Zn2SnO4 nanoparticles as anodes for lithium-ion batteries

Cited by 49 publications

References 49 publications

Recent Developments and Understanding of Novel Mixed Transition‐Metal Oxides as Anodes in Lithium Ion Batteries

Recent Developments and Understanding of Novel Mixed Transition‐Metal Oxides as Anodes in Lithium Ion Batteries

Electrochemical properties of MnS–C and MnO–C composite powders prepared via spray drying process

Zinc Stannate Nanostructures for Energy Conversion†

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Product

Resources

About

Zinc Stannate Nanostructures for Energy Conversion^†