Fused deposition modeling (FDM) 3D printing not only
offers numerous
advantages over traditional manufacturing methods but also produces
a significant amount of waste in the form of failed prints, support
structures, and unused filaments. Thus, there is a need to develop
novel and sustainable materials to replace conventional FDM filaments.
We report a unique biomass (waste leaves)-derived activated carbon
that can be infused with polyethylene terephthalate glycol (PETG)
to fabricate a sustainable, cost-effective, and eco-friendly class
of 3D printing filaments that enable 3D printing of parts with superior
mechanical properties. We investigate the key parameters that influence
the chemical, morphological, thermal, surface, and mechanical properties
of our biomass-derived hydrochar, activated carbon, and PETG composite
filaments. The resulting samples are characterized using Fourier transform
infrared spectroscope, X-ray diffraction, scanning electron microscope,
contact angle meter, and a universal testing machine. We have observed
that while hydrochar can be incorporated with PETG to create biomass-derived
filaments, incorporating activated carbon with PETG results in superior
filaments. These composites can incorporate an extremely high biomass
filler weight percentage while enhancing mechanical strength by over
30%. Our biomass-derived PETG composites were also thermally stable
and more hydrophilic than the pure PETG samples. We analyze the mechanism
by which activated carbon incorporation increases the PETG composites’
mechanical strength with both physical and chemical techniques. We
also demonstrate successful FDM 3D printing of personalized anatomical
models and porous cylindrical filter mesh using our biomass-derived
PETG composite filaments. Implementing such sustainable principles
in the 3D printing industry has the potential to transform it into
a restorative and sustainable system while simultaneously minimizing
environmental pollution and waste.