The current investigation focuses on Bi2Se3 films grown via a thermal evaporation process and subsequently
annealed
at temperatures of 100 °C, 150 °C, 200 °C, and 250
°C for 2 h. The structural study of the Bi2Se3 annealed film confirmed the crystalline nature of the material,
and crystallite sizes ranged between 14 and 24 nm. Annealing induced
enhanced porosity, which was observed through surface morphology analysis.
Optical studies revealed decreased transmission ability and increased
absorption capability with postannealing. The direct optical band
gap reduced from 1.269 to 1.144 eV at 250 °C due to increased
localized states within the gap. Annealing also led to an enhancement
in the extinction coefficient and optical density, alongside a reduction
in skin depth. The material’s refractive index gradually enhanced
with the increase in the annealing temperature. The refractive index
of the material gradually increased with higher annealing temperatures.
Additionally, the third-order susceptibility rose from 4.304 ×
10–11 to 5.661 × 10–11 esu,
resulting in an increase in the nonlinear refractive index from 5.152
× 10–10 to 6.575 × 10–10 esu, respectively. Moreover, annealing increased the hydrophobicity
of the films, rendering them as self-cleaning materials. The surface
energies of the materials lie between 14.05 and 4.49 mN/m. The augmented
photocurrent postannealing indicates potential applications in various
photodetector sectors. These findings, which highlight optical and
structural enhancements, underscore the suitability of these films
for optoelectronic devices.