Preparation and performance of (Co, Mn)₃O₄ spinel coating on Crofer alloy by composite electrodeposition and step‐heating thermal conversion

Abstract

The preparation and performance improvement of the spinel coating on the surface of ferritic alloy is of wide interest for its application in the metallic interconnects of the solid oxide fuel cells (SOFCs). The CoMn2O3 composite coating is prepared on the surface of the Crofer alloy by the composite electrodeposition method. A step‐heating thermal conversion process is subsequently used to convert the composite coating into a spinel coating, while a direct‐heating process is implemented as the control experiment. Isothermal oxidation tests are then carried out for the prepared samples in order to present the high temperature performance. Scanning electron microscopy (SEM), X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS), and area‐specific resistance (ASR) are used to analyze the properties of the matrix and coatings. The experimental results reveal that the coatings by step‐heating thermal conversion exhibit better performance of electrical conductivity and oxidation resistance than the coatings by direct‐heating process. Furthermore, with the increase of oxidation time, the atomic proportion of Cr element diffusing to the surface of the matrix is maintained at about 3%–4% for the samples with spinel coatings by step heating, which effectively prevent the Cr volatilization in the matrix. The preparation of spinel coatings on the ferritic alloy by composite electrodeposition and step‐heating thermal conversion is helpful to stimulate new ideas for the development of reliable and cost‐effective metallic interconnect.

Influences of Composite Electrodeposition Parameters on the Properties of Ni-Doped Co-Mn Composite Spinel Coatings

“…To overcome the above defects, protective coatings are often prepared on the surface of the FSS substrate to prevent the “Cr poisoning” of the cathodic, as well as improve the oxidation resistance and the conductivity of the SOFC. Among the protective coatings, Co-Mn spinel coatings have been paid more attention attributed to their high density, simple prepare methods and good electrical property et al [ 8 , 9 ].…”