Preparation and Properties of Acetoacetic Ester-Terminated Polyether Pre-Synthesis Modified Phenolic Foam

Ge, Tiejun; Tang, Kaihong; Tang, Xiaojun

doi:10.3390/ma12030334

Cited by 14 publications

(8 citation statements)

References 37 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…For example, we replaced a portion of phenol with m-pentadecylphenol to introduce a fifteen-carbon long chain into the phenolic resin structure [27]. After the acetyl acetate-terminated polyether was synthesized, it was introduced into the phenolic resin [28]. Copolymerization of polyethylene adipate glycol (PEA) was achieved during the synthesis of phenolic resin [29].…”

Section: Introductionmentioning

confidence: 99%

The Preparation and Properties of Terephthalyl-Alcohol-Modified Phenolic Foam with High Heat Aging Resistance

Tang

et al. 2019

Polymers

Self Cite

View full text Add to dashboard Cite

In this experiment, terephthalyl alcohol was used as a modifier to modify phenol under both acidic and alkaline conditions to obtain modified phenols with different molecular structures. Subsequently, the modified phenols reacted with paraformaldehyde in an alkaline environment. After foaming and curing, a modified phenolic foam with high heat aging resistance was obtained. The molecular structure was characterized via Fourier transform infrared spectrometry (FT-IR) and nuclear magnetic resonance spectroscopy (13C NMR). The results showed that two different structures of phenolic resin can be successfully prepared under different conditions of acid and alkali. The modified phenolic foam was tested by thermogravimetric analysis. In addition, the modified phenolic foam was tested for mass change rate, dimensional change rate, powdering rate, water absorption rate, and compressive strength before and after aging. The results show that the modified phenolic foam has excellent performance. After heat aging for 24 h, the mass loss rate of the modified phenolic foam obtained by acid catalysis was as low as 4.5%, the pulverization rate was only increased by 3.2%, and the water absorption of the modified phenolic foam increased by 0.77%, which is one-third that of the phenolic foam. Compared with the phenolic foam, the modified phenolic foam shows good heat aging resistance.

show abstract

Section: Introductionmentioning

confidence: 99%

The Preparation and Properties of Terephthalyl-Alcohol-Modified Phenolic Foam with High Heat Aging Resistance

Tang

et al. 2019

Polymers

Self Cite

View full text Add to dashboard Cite

show abstract

“…Therefore, reinforcement has been an important research direction of phenolic foam composites.In recent years, many researchers have conducted numerous studies on the strengthening of phenolic foam composites. The easiest and most convenient way to enhance phenolic foam is to blend some external toughening agents in phenolic resins, such as natural rubber, nitrile rubber [11][12][13][14], external flexures, and fiber materials, such as glass fiber [15][16][17]. Although the addition of rubber improves the toughness of PF, it reduces its heat resistance [18].…”

mentioning

confidence: 99%

Phenolic Resin Foam Composites Reinforced by Acetylated Poplar Fiber with High Mechanical Properties, Low Pulverization Ratio, and Good Thermal Insulation and Flame Retardant Performance

et al. 2019

View full text Add to dashboard Cite

Phenolic foam composites (PFs) are of substantial interest due to their uniform closed-cell structure, low thermal conductivity, and good thermal insulation performance. However, their disadvantages of a high pulverization rate and poor mechanical properties restrict their application in building exterior insulation. Therefore, the toughening of these composites is necessary. In this paper, poplar fiber was treated with an acetylation reagent, and the acetylated fiber was used to prepare modified phenolic foams (FTPFs); this successfully solved the phenomenon of the destruction of the foam structure due to the agglomeration of poplar fiber in the resin substrate. The foam composites were comprehensively evaluated via the characterization of their chemical structures, surface morphologies, mechanical properties, thermal conductivities, and flame retardant properties. It was found that the compressive strength and compressive modulus of FTPF-5% respectively increased by 28.5% and 37.9% as compared with those of PF. The pulverization ratio was reduced by 32.3%, and the thermal insulation performance and flame retardant performance (LOI) were improved. Compared with other toughening methods for phenolic foam composites, the phenolic foam composites modified with surface-compatibilized poplar fiber offer a novel strategy for the value-added utilization of woody fiber, and improve the toughness and industrial viability of phenolic foam.

show abstract

“…This was because the addition of EG enhanced the toughness of the MF foams, improved the toughness of the MF foams wall, and reduced the bursting of the foaming agent into the cell, which increased the cell closing. 37 It can be seen that the water absorption of the CF/EG composite modified MF foams declined slightly at first and then increased with further increasing of CF. When the CF content was 0.9 wt%, the water absorption reached the minimum.…”

Section: Water Absorption and Apparent Density Of Mf Rigid Foamsmentioning

confidence: 89%

Preparation and properties of melamine-formaldehyde rigid closed-cell foam toughened by ethylene glycol/carbon fiber

Zhou

et al. 2020

Cellular Polymers

View full text Add to dashboard Cite

Toughing melamine-formaldehyde (MF) rigid closed-cell foams were prepared by using ethylene glycol (EG) and carbon fiber (CF) as composite toughening agents. The pulverization rate, compressive strength, bending strength, cellular structure, closed-cell ratio, water absorption ratio, thermal conductivity, thermal stability, limiting oxygen index (LOI), and char yield were characterized to study the morphology, mechanical, thermal, and fire-retardant properties of as-prepared toughing MF rigid foams. The pulverization rate result showed that introduction of composite modifier can obviously improve the toughness of MF rigid foams. The cellular structure, closed-cell ratio, and water absorption results showed that the addition of EG/CF can increase the closed-cell ratio and control the cell size of MF rigid foams. The compressive strength and bending strength results showed that the incorporation of composite modifier of MF rigid foams dramatically improved the mechanical properties. The LOI, char yield, and thermal stability results showed that the toughing MF rigid foams remained more intact char skeleton with flame-retardant effect, thus reducing the fire hazards. The as-prepared toughing MF rigid foams showed the best comprehensive performance with pulverization rate of 5.21%, compressive strength of 355.3 kPa, bending strength of 0.44 MPa, closed-cell ratio of 79.1%, water absorption of 9%, thermal conductivity of 0.031 W m−1 K−1, and LOI of 39.6%. Compared with unmodified MF rigid foams, toughing rigid closed-cell MF foams possess excellent pulverization rate, compressive strength, bending strength, cellular structure, thermal insulation, and flame retardancy.

show abstract

Preparation and Properties of Acetoacetic Ester-Terminated Polyether Pre-Synthesis Modified Phenolic Foam

Cited by 14 publications

References 37 publications

The Preparation and Properties of Terephthalyl-Alcohol-Modified Phenolic Foam with High Heat Aging Resistance

The Preparation and Properties of Terephthalyl-Alcohol-Modified Phenolic Foam with High Heat Aging Resistance

Phenolic Resin Foam Composites Reinforced by Acetylated Poplar Fiber with High Mechanical Properties, Low Pulverization Ratio, and Good Thermal Insulation and Flame Retardant Performance

Preparation and properties of melamine-formaldehyde rigid closed-cell foam toughened by ethylene glycol/carbon fiber

Contact Info

Product

Resources

About