PREPARATION AND PROPERTIES OF MONOMERIC AND POLYMERIC ACRYLIC ESTERS OF ETHER-ALCOHOLS<sup>2</sup>

Rehberg, C. E.; Faucette, W. A.

doi:10.1021/jo01158a019

Cited by 10 publications

(2 citation statements)

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“…Powdered soy beans suspended in 0,05 N alcoholic alkali, at room temperature, give a good yield of the ethyl esters (71). Various lactic esters are made from methyl lactate by alcoholysis (41,132,135), Diallyl carbonate can be made from ethyl carbonate with sodium ethylate as catalyst (2). Alkyl zirconates are subject to alcoholysis (176).…”

Section: Alcoholysismentioning

confidence: 99%

Esterification

Reid¹

1951

Ind. Eng. Chem.

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Section: Alcoholysismentioning

confidence: 99%

Esterification

Reid¹

1951

Ind. Eng. Chem.

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“…Die Synthese des Acrylats 6 erfolgte analog 1 aus Heptamethyltrisiloxan, Allylchlorid und P-Hydroxyethylacrylat (6: K,O,' = 82 -84 "C, ng = 1,4183; Ausbeute 25 070). 8-Ethoxyethylacrylat 4 wurde nach [4]…”

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Photovernetzung von Siliconen. VII. Zum Einflu� der Siliconkette - eine kinetische Studie

Müller

Aguirre

1992

J. Prakt. Chem.

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Photocrosslinking of Silicones. VII. The Influence of the Silicone Backbone – a Kinetic Study The photo‐induced radical crosslinking of silicone containing pendant acrylate groups was investigated by nanosecond flash photolysis and photocalorimetry. From the results of the flash photolysis is inferred that the photochemically formed benzoyl radicals react with the acrylate groups of the system. A possible H‐abstraction from the methyl groups of the silicone backbone was not observed. The silicone backbone functions only as an internal solvent. Calorimetric measurements with model systems support these results. The polymerization process is inhibited by oxygen. From calorimetric results is inferred that oxygen both inhibits and terminates the polymerization process. Due to their high oxygen solubility the silicone units increase the oxygen influence on the crosslinking. The calorimetric measurements shows also that a direct bond between silicone backbone and the acrylate group reduces the oxygen influence. Also, in absence of oxygen a direct bonded acrylate group accelerates the polymerization rate.

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Acrylic Acid and Derivatives

Bauer

2000

Kirk-Othmer Encyclopedia of Chemical Technology

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Acrylic acid (propenoic acid) is prepared using acrolein from the catalytic oxidation of propylene. Acrylates are primarily used to prepare emulsion and solution polymers. The emulsion polymerization process provides high yields of polymers in a form suitable for a variety of applications. Acrylate emulsions are used in the preparation of paints, floor polishes, and adhesives. Solution polymers of acrylates are employed in the preparation of industrial coatings. The polymeric products share qualities of high resistance to chemical and environmental attack and attractive strength properties. Acrylic acid and its esters react readily with electrophilic, free‐radical, and nucleophilic agents.

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PREPARATION AND PROPERTIES OF MONOMERIC AND POLYMERIC ACRYLIC ESTERS OF ETHER-ALCOHOLS²

Cited by 10 publications

References 5 publications

Esterification

Esterification

Photovernetzung von Siliconen. VII. Zum Einflu� der Siliconkette - eine kinetische Studie

Acrylic Acid and Derivatives

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PREPARATION AND PROPERTIES OF MONOMERIC AND POLYMERIC ACRYLIC ESTERS OF ETHER-ALCOHOLS2

Cited by 10 publications

References 5 publications

Esterification

Esterification

Photovernetzung von Siliconen. VII. Zum Einflu� der Siliconkette - eine kinetische Studie

Acrylic Acid and Derivatives

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Product

Resources

About

PREPARATION AND PROPERTIES OF MONOMERIC AND POLYMERIC ACRYLIC ESTERS OF ETHER-ALCOHOLS²