Preparation and Properties of Polysilsesquioxanes-Preparation and Properties of Polymer Hybrids from Vinyltrimethoxysilane.

Polyvinylpolysilsesquioxane (PVPS) organic-inorganic hybrid gel films comprising polyethylene and siloxane backbone linkages were prepared through two routes: trimethoxy(vinyl)silane (VTS) was first subjected to radical polymerization of the vinyl groups, followed by acid-catalyzed hydrolytic polycondensation of the trimethoxysilyl groups (route A) to afford PVPS; in the second route PVPS was prepared in reverse order (route B). PVPS gel films were transparent and homogeneous. We find that the mechanical and heat-resisting properties correlate both to the degree of polymerization and the degree of cross-linking.

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Preparation and properties of organic–inorganic hybrid gel films based on polyvinylpolysilsesquioxane synthesized from trimethoxy(vinyl)silane

Gunji

Okonogi

Sakan

et al. 2003

Applied Organom Chemis

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Preparation and Properties of Organic-Inorganic Hybrid Gel Films Based on Polyvinylpolysilsesquioxane Synthesized from Trimethoxy(vinyl)silane

Gunji

Kawaguchi

Okonogi

et al. 2005

J Sol-Gel Sci Technol

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Preparation and characterization of stable DQ silicone polymer sols

Hayami

Nishikawa

Hisa

et al. 2018

J Sol-Gel Sci Technol

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Preparation and Properties of Polysilsesquioxanes-Preparation and Properties of Polymer Hybrids from Vinyltrimethoxysilane.

Cited by 8 publications

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Preparation and properties of organic–inorganic hybrid gel films based on polyvinylpolysilsesquioxane synthesized from trimethoxy(vinyl)silane

Preparation and properties of organic–inorganic hybrid gel films based on polyvinylpolysilsesquioxane synthesized from trimethoxy(vinyl)silane

Preparation and Properties of Organic-Inorganic Hybrid Gel Films Based on Polyvinylpolysilsesquioxane Synthesized from Trimethoxy(vinyl)silane

Preparation and characterization of stable DQ silicone polymer sols

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