In this work, stereocomplex-poly(L-and D-lactide) (sc-PLA) was incorporated into poly(e-caprolactone) (PCL) to fabricate a novel biodegradable polymer composite. PCL/sc-PLA composites were prepared by solution casting at sc-PLA loadings of 5-30 wt %. Differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD) demonstrated the formation of the stereocomplex in the blends. DSC and WAXD curves also indicated that the addition of sc-PLA did not alter the crystal structure of PCL. Rheology and mechanical properties of neat PCL and the PCL/sc-PLA composites were investigated in detail. Rheological measurements indicated that the composites exhibited evident solid-like response in the low frequency region as the sc-PLA loadings reached up to 20 wt %. Moreover, the long-range motion of PCL chains was highly restrained. Dynamic mechanical analysis showed that the storage modulus (E 0 ) of PCL in the composites was improved and the glass transition temperature values were hardly changed after the addition of sc-PLA. Tensile tests showed that the Young's modulus, and yield strength of the composites were enhanced by the addition of sc-PLA while the tensile strength and elongation at break were reduced.